From Wikipedia, the free encyclopedia
Class of chemical compounds
An iodide nitride is a
mixed anion compound containing both
iodide (I− ) and
nitride ions (N3− ). Another name is metalloiodonitrides . They are a subclass of halide nitrides or
pnictide halides .
[1] Some different kinds include ionic alkali or alkaline earth salts, small clusters where metal atoms surround a nitrogen atom, layered
group 4 element 2-dimensional structures (which could be exfoliated to a monolayer), and transition metal
nitrido complexes counter-balanced with iodide ions. There is also a family with rare earth elements and nitrogen and sulfur in a cluster.
Related mixed-anion compounds include halogen variations:
nitride fluoride ,
nitride chloride , and
nitride bromide , and pnictogen variations
phosphide iodide ,
arsenide iodide and
antimonide iodides .
Production
Nitride iodides may be produced by heating metal nitrides with metal iodides. The ammonolysis process heats a metal iodide with
ammonia .
[2] A related method heats a metal or metal hydride with
ammonium iodide . The nitrogen source could also be an
azide or an amide.
[2]
List
name
formula
formula weight
crystal system
space group
unit cell Å
volume
density
comments
ref
Li4 NCl
hexagonal
R 3
a =366.225 c =1977.18 Z=3
[3]
calcium nitride iodide
Ca2 NI
P63 /mmc
a = 3.8095, c = 14.530, Z = 2
[4]
α-TiNI
orthorhombic
Pmmn
a=3.941 b=3.51.5 c=8.955 Z=2
black
[5]
NCr(I)(Ni Pr2 )2
[6]
Cr(I)(N)(N(C(CD3 )2 CH3) (C6 H3 FMe))2
[7]
Zn2 NI
orthorhombic
Pnma
a=6.3590 b=6.2529 c=7.9549
<6 GPa
[8]
strontium nitride iodide
Sr2 NI
316.15
trigonal
R 3 m
a = 4.0049 c = 23.055 Z=3
320.24
4.918
orange
[9]
α-ZrNI
orthorhombic
Pmmn
a=4.114 b=3.724 c=9.431 Z=2
orange
[10]
[5]
β-ZrNI
trigonal
R 3 m
a=3.718 c=31.381 Z=6
brown
[5]
[(pcp)Mo(IV) (N)(I)][Na(15-crown-5)] pcp=C6 H3 (OPiPr2 )2
[11]
Ba2 NI
LiLa4 N2 I7
orthorhombic
Pnma
a = 13.7417, b = 12.1345, c = 10.7991 Z=4
@100K
[12]
NaLa4 N2 I7
orthorhombic
Pna 21
a =14.0018 b =10.9315 c =12.1021 Z =4
5.361
colourless air sensitive
[13]
Ce15 N7 I24
4245.6
orthorhombic
Pnma
a=12.060 b=32.216 c=16.360 Z=4
5.48
red; air sensitive
[14]
NaCe4 N2 I7
orthorhombic
Pna 21
a =13.9703 b=10.8932 c=12.0194 Z =4
5.446
red air sensitive
[13]
NaPr4 N2 I7
orthorhombic
Pna 21
a =13.9412 b=10.8578 c=11.9389 Z =4
5.524
yellowish green air sensitive
[13]
NaNd4 N2 I7
orthorhombic
Pna 21
a =13.9135 b=10.86 c=11.86 Z =4
5.638
pinkish blue air sensitive
[13]
(NdI2 )3 N
[15]
(NdI2 )3 N(DME)4
[16]
NdI(S2 N2 )(THF)
[17]
Nd3 I5 (S2 N2 )(S2 )(THF)10
2088.72
monoclinic
P 21
a =12.393 b=43.389 c=12.684 β= 90.013 Z=4
6820
2.034
yellow
[15]
Ln3 I5 (S2 )(S2 N2 )(THF)4 (Phen)3
[18]
Ln3 I5 (S2 )(S2 N2 )(THF)3(Py)7
[18]
(SmI)3 N2 (THF)
[16]
ErI(S2 N2 )(THF)
[17]
Nd2 ErClI4 -(S2 )(S2 N2 )(THF)7
[17]
Nd2 ErCl2 I3 (S2 )(S2 N2 )(THF)7
[17]
(DyI2 )3 N
[19]
Dy3 I5 (S2 )(S2 N2 )(THF)10
[19]
Nd2 DyI5 (S2 )(S2 N2 )(THF)7
[17]
Nd2 DyI5 (S3 )(S2 N2 )(THF)9
2034.88
monoclinic
P 21 /c
a=23.1102 b=12.6551 c=23.8268 β =111.201 Z=4
6496.8
2.080
[20]
Nd2 TbI5 (S2 )(S2 N2 )(THF)9
monoclinic
P 21 /c
a =23.1704 b =12.6340 c =23.8340, β =111.274° Z=4
[21]
Nd2 TmI5 (S2 )(S2 N2 )(THF)9
monoclinic
P 21 /c
a =23.075 b =12.6540 c =23.809, β =111.460° Z=4
[21]
Nd2 YbI5 (S3 )(S2 N2 )(THF)9
monoclinic
P 21 /c
a=23.0959 b=12.6632 c=23.8387 β =111.363 Z=4
6493.0
2.092
[20]
α-HfNI
orthorhombic
Pmmn
a=4.10.67 b=3.6944 c=9.382 Z=2
[5]
[10]
β-HfNI
trigonal
R 3 m
a=3.689 c=31.329 Z=6
brown
[5]
ThNI
tetragonal
P 4/nmm
a=4.107 c=9.242
orange to golden grey
[5]
[22]
UNI
tetragonal
P 4/nmm
a=3.99 c=9.20 Z=2
[5]
[23]
References
^ Headspith, David A.; Francesconi, M. Grazia (October 2009).
"Transition Metal Pnictide-Halides: A Class of Under-Explored Compounds" . Topics in Catalysis . 52 (11): 1611–1627.
doi :
10.1007/s11244-009-9282-5 .
ISSN
1022-5528 .
S2CID
93522549 .
^
a
b Schurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011).
"Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)" . Zeitschrift für Kristallographie . 226 (4): 395.
Bibcode :
2011ZK....226..395S .
doi :
10.1524/zkri.2011.1350 .
ISSN
0044-2968 .
S2CID
93973409 .
^ Marx, Rupert (February 1997).
"Preparation and Crystal Structure of Lithium Nitride Chloride Li4NCl" . Journal of Solid State Chemistry . 128 (2): 241–246.
Bibcode :
1997JSSCh.128..241M .
doi :
10.1006/jssc.1996.7196 .
^ Hadenfeldt, C.; Herdejürgen, H. (February 1987).
"Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr" . Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183.
doi :
10.1002/zaac.19875450220 .
ISSN
0044-2313 .
^
a
b
c
d
e
f
g Schurz, Christian M.; Shlyk, Larysa; Schleid, Thomas; Niewa, Rainer (January 2011).
"Superconducting nitride halides MNX (M = Ti, Zr, Hf; X = Cl, Br, I)" . Zeitschrift für Kristallographie . 226 (4): 395.
Bibcode :
2011ZK....226..395S .
doi :
10.1524/zkri.2011.1350 .
ISSN
0044-2968 .
S2CID
93973409 .
^ Odom, Aaron L.; Cummins, Christopher C. (1996-02-06).
"A Chromium(VI) Nitrido−Silylmethyl Complex and a Chromium(V) μ-Nitrido Dimer: Synthetic and Structural Details" . Organometallics . 15 (3): 898–900.
doi :
10.1021/om950842k .
ISSN
0276-7333 .
^ Mindiola, Daniel J.; Cummins, Christopher C. (1998). "Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex". Angewandte Chemie International Edition . 37 (7): 945–947.
doi :
10.1002/(SICI)1521-3773(19980420)37:7<945::AID-ANIE945>3.0.CO;2-X .
PMID
29711483 .
^ Li, Xiaofeng; Xue, Lin; Tang, Lijuan; Hu, Ziyu (2015).
"Pressure modulates the phase stability and physical properties of zinc nitride iodine" . RSC Advances . 5 (96): 78754–78759.
Bibcode :
2015RSCAd...578754L .
doi :
10.1039/C5RA14426D .
ISSN
2046-2069 .
^ Bailey, Andrew S.; Gregory, Duncan H.; Hubberstey, Peter; Wilson, Claire (2007-09-15).
"Crystal growth and redetermination of strontium nitride iodide, Sr 2 NI" . Acta Crystallographica Section E . 63 (9): i177.
doi :
10.1107/S1600536807039797 .
ISSN
1600-5368 .
^
a
b Yamanaka, Shoji; Itoh, Kojiro; Fukuoka, Hiroshi; Yasukawa, Masahiro (2000-02-01).
"High-Pressure Synthesis of the Polymorph of Layer Structured Compounds MNX (M = Zr, Hf; X = Cl, Br, I)" . Inorganic Chemistry . 39 (4): 806–809.
doi :
10.1021/ic991058l .
ISSN
0020-1669 .
PMID
11272580 .
^ Song, Jinyi; Liao, Qian; Hong, Xin; Jin, Li; Mézailles, Nicolas (2021-05-25).
"Conversion of Dinitrogen into Nitrile: Cross‐Metathesis of N 2 ‐Derived Molybdenum Nitride with Alkynes" . Angewandte Chemie International Edition . 60 (22): 12242–12247.
doi :
10.1002/anie.202015183 .
ISSN
1433-7851 .
PMID
33608987 .
S2CID
231969654 .
^ Schurz, Christian M.; Niewa, Rainer; Schleid, Thomas (January 2020).
"LiLa4N2I7 as the first lithium-containing nitride halide of the lanthanides: Synthesis, crystal structure and spectroscopic characterization" . Solid State Sciences . 99 : 106047.
Bibcode :
2020SSSci..9906047S .
doi :
10.1016/j.solidstatesciences.2019.106047 .
S2CID
209706784 .
^
a
b
c
d Schurz, Christian M.; Schleid, Thomas (October 2010).
"The first quaternary lanthanide(III) nitride iodides: NaM4N2I7 (M=La–Nd)" . Journal of Solid State Chemistry . 183 (10): 2253–2260.
Bibcode :
2010JSSCh.183.2253S .
doi :
10.1016/j.jssc.2010.07.025 .
^ Mattausch, Hansj Ürgen; Kremer, Reinhard K.; Simon, Arndt (April 1996).
"Synthese, Kristallstruktur und magnetische Eigenschaften von Ce15N7I24" . Zeitschrift für anorganische und allgemeine Chemie (in German). 622 (4): 649–654.
doi :
10.1002/zaac.19966220413 .
ISSN
0044-2313 .
^
a
b Fagin, A. A.; Fukin, G. K.; Cherkasov, A. V.; Shestakov, A. F.; Pushkarev, A. P.; Balashova, T. V.; Maleev, A. A.; Bochkarev, M. N. (2016).
"Ln 3 I 5 (S 2 N 2 )(S 2 )(THF) 10 – a new type of molecular compounds" . Dalton Transactions . 45 (11): 4558–4562.
doi :
10.1039/C5DT04742K .
ISSN
1477-9226 .
PMID
26842841 .
^
a
b Kuzyaev, Dmitry M.; Maleev, Alexander A.; Kulikova, Tatyana I.; Vorozhtsov, Dmitry L.; Bochkarev, Mikhail N. (February 2017).
"Reactivity of Neodymium and Samarium Nitrides" . Journal of Chemical Research . 41 (2): 82–84.
doi :
10.3184/174751917X14839766277332 .
ISSN
1747-5198 .
S2CID
99205962 .
^
a
b
c
d
e Fagin, A. A.; Kuznetsova, O. V.; Rumyantsev, R. V.; Baranov, E. V.; Fukin, G. K.; Bochkarev, M. N. (March 2022).
"Lanthanide Iodide Nitride Sulfide Clusters" . Russian Journal of Coordination Chemistry . 48 (3): 146–152.
doi :
10.1134/S1070328422020026 .
ISSN
1070-3284 .
S2CID
247387448 .
^
a
b Fagin, A. A.; Kuzyaev, D. M.; Burin, M. A.; Kuznetsova, O. V.; Khamaletdinova, N. M.; Kulikova, T. I.; Shestakov, A. F.; Lopatina, T. I.; Vorozhtsov, D. L.; Bochkarev, M. N. (February 2018).
"On the Reactivity and Stability of Iodide–Nitride–Sulfide Clusters of Neodymium and Dysprosium" . Russian Journal of Coordination Chemistry . 44 (2): 127–131.
doi :
10.1134/S1070328418020045 .
ISSN
1070-3284 .
S2CID
103790629 .
^
a
b Fagin, A.A.; Kuznetsova, O.V.; Balashova, T.V.; Cherkasov, A.V.; Fukin, G.K.; Bochkarev, M.N. (January 2018).
"Iodide-sulfides of dysprosium: Elucidation of the pathway to lanthanide iodide-sulfide-nitride clusters" . Inorganica Chimica Acta . 469 : 227–230.
doi :
10.1016/j.ica.2017.09.030 .
^
a
b Fagin, A. A.; Kuznetsova, O. V.; Rumyantcev, R. V.; Fukin, G. K.; Marugin, A. V.; Bochkarev, M. N. (September 2019).
"Neodymium–Dysprosium and Neodymium–Ytterbium Iodide–Sulfide–Nitride Clusters: Synthesis and Luminescence" . Journal of Cluster Science . 30 (5): 1277–1281.
doi :
10.1007/s10876-019-01552-5 .
ISSN
1040-7278 .
S2CID
146044754 .
^
a
b Fagin, A.A.; Kuzyaev, D.M.; Maleev, A.A.; Baranov, E.V.; Rumyantcev, R.V.; Fukin, G.K.; Shestakov, A.F.; Suchkov, A.I.; Marugin, A.V.; Bochkarev, M.N. (May 2019).
"Heterolanthanide three-nuclear iodide-sulfide-nitride clusters. Unusual synthesis way and structure" . Inorganica Chimica Acta . 490 : 200–203.
doi :
10.1016/j.ica.2019.03.021 .
S2CID
107891753 .
^ Juza, Robert; Sievers, Rolf (December 1968).
"Nitridhalogenide des Thoriums" . Zeitschrift für anorganische und allgemeine Chemie (in German). 363 (5–6): 258–272.
doi :
10.1002/zaac.19683630505 .
ISSN
0044-2313 .
^ Juza, R.; Meyer, W. (April 1969).
"Über Uran-Nitrid-Chlorid, -Bromid und -Jodid" . Zeitschrift für anorganische und allgemeine Chemie (in German). 366 (1–2): 43–50.
doi :
10.1002/zaac.19693660105 .
ISSN
0044-2313 .
Salts and covalent derivatives of the
iodide ion
Salts and covalent derivatives of the
nitride ion