Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I−) and antimonide (Sb3−). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.
List
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|---|---|---|---|---|---|---|
| Ge38Sb8I8 | cubic | Pm3n | a=10.8892 | clathrate; band gap 1.16 eV; thermal conductivity 7 mWcm−1K−1 | [1] | ||
| Cd4Sb2I3 | cubic | Pa3 | a=13.48 | [2] | |||
| Sn38Sb8I8 | cubic | Pm3n | a=12.0447 | clathrate; band gap 0.80 eV; thermal conductivity 12mWcm−1K−1 | [1] | ||
| La2SbI2 | rhombohedral | a=4.530 c=32.80 | [3] | ||||
| Hg5Sb2I6 | orthorhombic | Pc21n | a=8.108, b=10.702, c=21.295 | 1847.7 | 7.217 | Dark red | [4] |
| (Hg6Sb4)(CdI6) | rhombohedral | R3c | a = 13.3818, α = 90.93°, | 2395.3 | 7.111 | black | [5] |
| (Hg6Sb4)(CdI6)Hg0.6 | cubic | Pa3 | a=13.234 | 2317.7 | 7.604 | black; band gap 1.23; air stable | [6] |
| [Hg6Sb4I3](SnI3)Hg0.16 | cubic | P213 | a=13.285 Z=4 | [7] |
References
- ^ a b Kishimoto, Kengo; Arimura, Shuntaro; Koyanagi, Tsuyoshi (2006-05-29). "Preparation and thermoelectric properties of sintered iodine-containing clathrate compounds Ge38Sb8I8 and Sn38Sb8I8". Applied Physics Letters. 88 (22): 222115. Bibcode: 2006ApPhL..88v2115K. doi: 10.1063/1.2209207. ISSN 0003-6951.
- ^ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe". Solid State Communications. 255–256: 5–10. Bibcode: 2017SSCom.255....5R. doi: 10.1016/j.ssc.2017.03.001.
- ^ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi: 10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
- ^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (February 1994). "Synthesis and Crystal Structure of Hg5Sb2I6". Zeitschrift für anorganische und allgemeine Chemie (in German). 620 (2): 389–392. doi: 10.1002/zaac.19946200232. eISSN 1521-3749. ISSN 0044-2313.
- ^ Zou, Jian-Ping; Li, Yan; Zhang; Guo; Liu, Xi; Wang, Ming-Sheng; Cai, Li-Zhen; Lu, Ying-Bing; Huang, Jin-Shun (2007-09-01). "Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg 6 Sb 4 )(CdI 6 )". Inorganic Chemistry. 46 (18): 7321–7325. doi: 10.1021/ic0624165. ISSN 0020-1669. PMID 17665902.
- ^ Zou, Jian‐Ping; Li, Yan; Fu, Ming‐Lai; Guo, Guo‐Cong; Xu, Gang; Liu, Xue‐Hui; Zhou, Wei‐Wei; Huang, Jin‐Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)". European Journal of Inorganic Chemistry. 2007 (7): 977–984. doi: 10.1002/ejic.200600894. ISSN 1434-1948.
- ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi: 10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.