From Wikipedia, the free encyclopedia
Class of chemical compounds
Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I− ) and arsenide (As3− ). They can be considered as
mixed anion compounds . They are in the category of
pnictidehalides . Related compounds include the
arsenide chlorides ,
arsenide bromides ,
phosphide iodides , and
antimonide iodides .
List
formula
system
space group
unit cell Å
volume
density
comment
ref
Ca2 AsI
trigonal
R 3 m
a=4.397, c = 22.29, Z = 3
3.76
brown
[1]
[2]
Ca3 AsI3
cubic
I 41 32
a=12.42
3.99
colourless
[1]
Cu2 P1.8 As1.2 I2
monoclinic
P 21 /c
a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16
Cu exchangeable with Ag; band gap 1.2 eV
[3]
Ge38 As8 I8
cubic
P 4 3m
a=10.611
metallic; water and air stable
[4]
Ag2 P1.8 As1.2 I2
monoclinic
P 21 /c
a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16
[5]
Sn24 As19.3 I8
cubic
a=22.179 Z=8
black
[6]
Sn20.5 □3.5 As22 I8
cubic
a =22.1837
low thermal conductivity
[7]
Sn24 Asx P19.3−x I8 x=0-16
cubic
Pm3n
a = 10.9358—11.1495
[8]
Sn19.3 Cu4.7 As22 I8
cubic
Pm 3 n
a = 11.1736 Z = 1
1394.4
6.236
clathrate; Zintl; diamagnetic
[9]
Sn24–x –δ Inx As22–y I8
cubic
Pm 3 n
a = 11.088 (x = 0) to a = 11.343 (x = 10.7)
clathrate
[10]
La2 AsI2
trigonal
P 3 m1
a=4.3795 c=10.910
5.56
[11]
Hg4 AsI5
orthorhombic
Cmca
a=11.927 b=12.128 c=19.776 Z=8
2859.0
7.025
red
[12]
Hg4 As2 I3
cubic
Pa 3
a=12.999 Z=8
2196
8.06
black
[13]
HgI2 ⋅As4 S4
monoclinic
P 21 /c
a=9.433 b=14.986 c=11.624 β =127.72° Z=4
1299
4.509
orange; dec 212 °C
[14]
Hg5 AsS2 I3
monoclinic
C 2/c
a=13.339 b=8.444 c=13.428 β =118.352 Z=4
1331.2
7.599
black; dec 150 °C
[15]
Hg3 AsSe4 I
hexagonal
P 63 mc
a = 7.6902, c = 9.968 Z=2
red; air stable
[16]
[Hg7 As4 ](AgI3 )2
cubic
Pa
a = 13.138 Z = 4
[17]
[18]
(Hg2 As)2 (CdI4 )
monoclinic
P 21
a =7.945, b =12.934, c =8.094, β =116.898°
741.7
[19]
[Hg7 As4 I3 ](SnI3 )
cubic
P 21 3
a = 13.110, Z = 4
2253.2
7.617
black
[20]
References
^
a
b Hadenfeldt, C.; Fester, W. (July 1982).
"Reindarstellung und thermische Stabilität von Calcium-phosphid- und -arsenidiodiden: Ca3PI3, Ca3AsI3, Ca2PI und Ca2AsI" . Zeitschrift für anorganische und allgemeine Chemie (in German). 490 (1): 25–30.
doi :
10.1002/zaac.19824900105 .
ISSN
0044-2313 .
^ Hadenfeldt, C.; Herdejürgen, H. (February 1987).
"Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr" . Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183.
doi :
10.1002/zaac.19875450220 .
ISSN
0044-2313 .
^ Jayasekera, Buddhimathie; Aitken, Jennifer A.; Heeg, Mary Jane; Brock, Stephanie L. (2003-02-01).
"Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu 2 P 1.8 As 1.2 I 2" . Inorganic Chemistry . 42 (3): 658–660.
doi :
10.1021/ic0258936 .
ISSN
0020-1669 .
PMID
12562174 .
^ von Schnering, Hans-Georg; Menke, Heinz (January 1972).
"Ge38P8I8 and Ge38As8I8, a New Class of Compounds with Clathrate Structure" . Angewandte Chemie International Edition in English . 11 (1): 43–44.
doi :
10.1002/anie.197200431 .
ISSN
0570-0833 .
^ Jayasekera, Buddhimathie; Brock, Stephanie L. (2002).
"Ag Ion-Exchange Reactions of Cu 2 P 3 I 2 and Cu 2 P 1.8 As 1.2 I 2" . MRS Proceedings . 755 : DD6.12.
doi :
10.1557/PROC-755-DD6.12 .
ISSN
0272-9172 .
^ Shatruk, Mikhail M.; Kovnir, Kirill A.; Shevelkov, Andrei V.; Presniakov, Igor A.; Popovkin, Boris A. (1999-07-01).
"First Tin Pnictide Halides Sn 24 P 19.3 I 8 and Sn 24 As 19.3 I 8 : Synthesis and the Clathrate-I Type of the Crystal Structure" . Inorganic Chemistry . 38 (15): 3455–3457.
doi :
10.1021/ic990153r .
ISSN
0020-1669 .
PMID
11671088 .
^ Zaikina, Julia V.; Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Prots, Yuri; Baitinger, Michael; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Grin, Yuri (2007-06-15).
"Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivity" . Chemistry - A European Journal . 13 (18): 5090–5099.
doi :
10.1002/chem.200601772 .
PMID
17385200 .
^ Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009).
"Distribution of phosphorus and arsenic atoms in the solid solution Sn24As x P19.3-x I8 with the structure of clathrate-I" . Russian Chemical Bulletin . 58 (4): 746–750.
doi :
10.1007/s11172-009-0089-0 .
ISSN
1066-5285 .
S2CID
93897495 .
^ Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Schnelle, Walter; Grin, Yuri; Shevelkov, Andrei V. (2005-11-01).
"Sn 19.3 Cu 4.7 As 22 I 8 : a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework" (PDF) . Inorganic Chemistry . 44 (24): 8786–8793.
doi :
10.1021/ic051160k .
ISSN
0020-1669 .
PMID
16296833 .
^ Kelm, Evgeny A.; Olenev, Andrei V.; Bykov, Mikhail A.; Sobolev, Alexey V.; Presniakov, Igor A.; Kulbachinskii, Vladimir A.; Kytin, Vladimir G.; Shevelkov, Andrei V. (November 2011).
"Synthesis, Crystal Structure, and Thermoelectric Properties of Clathrates in the Sn-In-As-I System" . Zeitschrift für anorganische und allgemeine Chemie . 637 (13): 2059–2067.
doi :
10.1002/zaac.201100287 .
^ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01).
"Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" . Zeitschrift für Naturforschung B . 62 (11): 1377–1382.
doi :
10.1515/znb-2007-1105 .
ISSN
1865-7117 .
S2CID
95077294 .
^ Oleneva, O. S.; Shestimerova, T. A.; Olenev, A. V.; Dikarev, E. V.; Shevelkov, A. V. (May 2006).
"Synthesis and the crystal and electronic structure of Hg4AsI5" . Russian Chemical Bulletin . 55 (5): 762–765.
doi :
10.1007/s11172-006-0329-5 .
ISSN
1066-5285 .
S2CID
97240594 .
^ Labbé, Ph.; Ledésert, M.; Raveau, B.; Rebbah, A. (1989-08-01).
"Crystal structure of Hg 4 As 2 I 3" . Zeitschrift für Kristallographie - Crystalline Materials . 187 (1–4): 117–124.
doi :
10.1524/zkri.1989.187.14.117 .
ISSN
2196-7105 .
S2CID
101349696 .
^ Bräu, Michael F.; Pfitzner, Arno (2006-07-03).
"HgI2⋅As4S4: An Adduct from HgI2 Molecules and Undistorted As4S4 Cages" . Angewandte Chemie International Edition . 45 (27): 4464–4467.
doi :
10.1002/anie.200600690 .
ISSN
1433-7851 .
PMID
16758498 .
^ Liu, Yong; Zeng, Hui-Yi; Liu, Bin-Wen; Wang, Geng-E; Guo, Guo-Cong (May 2015).
"Hg 5 AsS 2 I 3 – A Narrow-Band-Gap 2D Layered Compound with Different Trapped I – Anions" . European Journal of Inorganic Chemistry . 2015 (14): 2402–2406.
doi :
10.1002/ejic.201500150 .
ISSN
1434-1948 .
^ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01).
"Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure" . Inorganic Chemistry . 39 (25): 5847–5850.
doi :
10.1021/ic0003527 .
ISSN
0020-1669 .
PMID
11151388 .
^ Olenev, Andrei V.; Baranov, Alexei I.; Oleneva, Olga S.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Shevelkov, Andrei V. (March 2003).
"Synthesis, Crystal and Electronic Structure of [Hg 7 As 4 ](AgI 3 ) 2 , a Novel Supramolecular Complex with the Off-Plane AgI 3 2− Guest Anion" . European Journal of Inorganic Chemistry . 2003 (6): 1053–1057.
doi :
10.1002/ejic.200390137 .
ISSN
1434-1948 .
^ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020).
"Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups" . Journal of Structural Chemistry . 61 (2): 259–266.
doi :
10.1134/S0022476620020109 .
ISSN
0022-4766 .
S2CID
220540955 .
^ Zou, Jian-Ping; Wu, Dong-Sheng; Huang, Shu-Ping; Zhu, Jing; Guo, Guo-Cong; Huang, Jin-Shun (March 2007).
"Synthesis, crystal and band structures, and properties of a new supramolecular complex (Hg2As)2(CdI4)" . Journal of Solid State Chemistry . 180 (3): 805–811.
Bibcode :
2007JSSCh.180..805Z .
doi :
10.1016/j.jssc.2006.11.018 .
^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2000). "[Hg7As4I3](SnI3): Trapping the SnI31– Anion in the Cavities of the Unprecedented Mercury-Arsenic-Iodine Network". European Journal of Inorganic Chemistry . 2000 (2): 265–270.
doi :
10.1002/(SICI)1099-0682(200002)2000:2<265::AID-EJIC265>3.0.CO;2-A .
Salts and covalent derivatives of the
iodide ion