Nitride fluorides containing
nitride and
fluoride ions with the formula NF4-. They can be electronically equivalent to a pair of
oxide ions O24-. Nitride fluorides were discovered in 1996 by Lavalle et al. They heated diammonium technetium hexafluoride to 300 °C to yield TcNF.[1] Another preparation is to heat a fluoride compound with a nitride compound in a solid state reaction.[2] The fluorimido ion is F-N2- and is found in a
rhenium compound.[3]
^
abNoetzel, Gerd; Schweda, Eberhard; Wiemhöfer, Hans-Dieter (February 2010). "Ionic Conductivity of Ce3NF6". Zeitschrift für anorganische und allgemeine Chemie. 636 (2): 389–394.
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^Dehnicke, Kurt.; Straehle, Joachim. (May 1993). "N-Halogenoimido complexes of transition metals". Chemical Reviews. 93 (3): 981–994.
doi:
10.1021/cr00019a007.
ISSN0009-2665.
^Westland, Alan D. (February 1973). "The reaction of chromium(II) fluoride with nitrogen". Journal of Inorganic and Nuclear Chemistry. 35 (2): 451–456.
doi:
10.1016/0022-1902(73)80556-1.
^Ashcraft, Richard Henry (1982). PREPARATION OF NEW METAL NITRIDE-FLUORIDES AND OTHER HIGH-TEMPERATURE STUDIES (Thesis thesis).
hdl:
1911/15665.
^Stoltz, C.; Ramesha, K.; Piccoli, P.; Toby, B. H.; Eichhorn, B. W. (October 2005). "A 0.3 ZrNF 1.3 Phases (A = Na, K) with Layered ZrNCl-Type Structures Prepared by Anion Metathesis". Chemistry of Materials. 17 (21): 5291–5296.
doi:
10.1021/cm051018h.
ISSN0897-4756.
^Pust, Philipp; Schnick, Wolfgang (September 2011). "LiSr2[TaN3]F – a Single Chain Nitridotantalate". Zeitschrift für anorganische und allgemeine Chemie. 637 (11): 1486–1489.
doi:
10.1002/zaac.201100207.
^Hofmann, M.; Schweda, E.; Strähle, J.; Laval, J.P.; Frit, B.; Estermann, M.A. (January 1995). "Synthesis and Structure of Bi3NF6: A Member with n = 3 of the Vernier Phases MnX2n+1". Journal of Solid State Chemistry. 114 (1): 73–78.
Bibcode:
1995JSSCh.114...73H.
doi:
10.1006/jssc.1995.1011.
^
abcSeel, F.; Langer, J. (July 1958). "Über Phosphornitrilfluoride. I". Zeitschrift für anorganische und allgemeine Chemie (in German). 295 (5–6): 316–326.
doi:
10.1002/zaac.19582950506.
ISSN0044-2313.
^Jagodzinski, H.; Langer, J.; Oppermann, I.; Seel, F. (November 1959). "Über Phosphornitrilfluoride. II. Zur Struktur und Kristallographie der Phosphornitrilfluoride". Zeitschrift für anorganische und allgemeine Chemie (in German). 302 (1–2): 81–87.
doi:
10.1002/zaac.19593020108.
ISSN0044-2313.