From Wikipedia, the free encyclopedia
Iodide hydrides are
mixed anion compounds containing
hydride and
iodide anions.
Many iodide hydrides are
cluster compounds , containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.
List
formula
system
space group
unit cell Å
volume
density
comment
reference
(Dipp Nacnac)Mg(μ-H)(μ-I)Mg(Mes Nacnac)
[1]
KHI
[2]
[3]
[LZnI(η2 -H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine
[4]
Sr2 H3 I
trigonal
P 3 m 1
a = 4.260 c = 7.749 Z=1
121.77
4.16
transparent
[5]
YIH
C=31.033
metallic
[6]
YIH2
P 3m 1
a = 3.8579, c = 10.997
light green
[6]
Nb6 I11 H
D10/2h
a = 11.317; b = 15.471 ; c = 13.431
[7]
Nb6 I11 H
Im 3 m
a = 11.317; b = 15.471 ; c = 13.431
black
[7]
Nb6 (H)I9 S
triclinic
P 1
a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2
[8]
[9]
HCsNb6 I11
[10]
Ba2 H3 I
trigonal
P 3 m 1
a= 4.519 c= 8.1184
transparent
[11]
Ba5 H2 I4 O2
orthorhombic
Cmcm
a =17.210, b = 14.525 c = 6.3903 Z=4
1597.44
5.11
transparent
[5]
LaI2 H
hexagonal
P 63 /mmc
a =4.2158 c =15.508
[12]
[13]
NdI2 H
[14]
Gd2 ICH0.73
P 63 mc
a=3.8128 C=14.844 Z=2
8.071
[15]
Eu2 H3 I
dark red
[16]
Eu5 H2 O2 I4
orthorhombic
Cmcm
a = 16.3697, b = 13.6954, c = 6.0436, Z = 4
dark red
[16]
Tb2 ICH
[15]
DyI2 H
[14]
[(η5 -C5 H5 )W(NO)IH]2
[17]
(η5 -C5 H5 )W(NO)I(H)(P(OPh)3 )
Ir(η2 -H2 )(H)2 I(Pi Pr3 )2
[18]
[19]
Ir(η2 -H2 )(H)2 I(Pi Pr3 )2 •C10 H8
triclinic
P 1
a=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=2
15K
[19]
References
^ Jones, Cameron; Stasch, Andreas (2013), Harder, Sjoerd (ed.),
"Stable Molecular Magnesium(I) Dimers: A Fundamentally Appealing Yet Synthetically Versatile Compound Class" , Alkaline-Earth Metal Compounds , Topics in Organometallic Chemistry, vol. 45, Berlin, Heidelberg: Springer Berlin Heidelberg, pp. 73–101,
doi :
10.1007/978-3-642-36270-5_3 ,
ISBN
978-3-642-36269-9 , retrieved 2023-11-15
^ Mills, R (November 2001).
"Minimum heat of formation of potassium iodo hydride" . International Journal of Hydrogen Energy . 26 (11): 1199–1208.
doi :
10.1016/S0360-3199(01)00051-9 .
^ Mills, R (December 2000).
"Synthesis and characterization of potassium iodo hydride" . International Journal of Hydrogen Energy . 25 (12): 1185–1203.
doi :
10.1016/S0360-3199(00)00037-9 .
^ Lummis, Paul Ashley (2015). Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis . University of Alberta.
^
a
b Reckeweg, Olaf; DiSalvo, Francis J. (2011-01-01).
"AlkalineEarthMetal-Hydride-Iodide Compounds: Syntheses andCrystal Structures of Sr 2 H 3 I and Ba 5 H 2 I 3.9(2) O 2" . Zeitschrift für Naturforschung B . 66 (1): 21–26.
doi :
10.1515/znb-2011-0104 .
ISSN
1865-7117 .
S2CID
27301598 .
^
a
b Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (August 2004).
"YIH n : A New Family of Metal-rich Hydride Halides" . Zeitschrift für anorganische und allgemeine Chemie . 630 (10): 1401–1407.
doi :
10.1002/zaac.200400094 .
ISSN
0044-2313 .
^
a
b Simon, Arndt (December 1967). "Beiträge zur Chemie der Elemente Niob und Tantal. LXV. HNb6J11 Eine Verbindung mit der komplexen Gruppe [HNb6J8]". Zeitschrift für anorganische und allgemeine Chemie . 355 (5–6): 311–322.
doi :
10.1002/zaac.19673550511 .
^ Meyer, H. Juergen; Corbett, John D. (October 1992).
"Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S)" . Inorganic Chemistry . 31 (21): 4276–4280.
doi :
10.1021/ic00047a013 .
ISSN
0020-1669 .
^ Meyer, H. Juergen; Corbett, John D. (March 1991).
"Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride" . Inorganic Chemistry . 30 (5): 963–967.
doi :
10.1021/ic00005a017 .
ISSN
0020-1669 .
^ Simon, Arndt (March 1985).
"Empty, filled, and condensed metal clusters" . Journal of Solid State Chemistry . 57 (1): 2–16.
Bibcode :
1985JSSCh..57....2S .
doi :
10.1016/S0022-4596(85)80055-4 .
^ Reckeweg, Olaf; DiSalvo, Francis J. (2011-11-01).
"Filling up another Gap: Synthesis and Crystal Structure of Ba 2 H 3 I" . Zeitschrift für Naturforschung B . 66 (11): 1087–1091.
doi :
10.1515/znb-2011-1101 .
ISSN
1865-7117 .
S2CID
40246199 .
^ Imoto, Hideo; Corbett, John D. (February 1981).
"Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures" . Inorganic Chemistry . 20 (2): 630–633.
doi :
10.1021/ic50216a062 .
ISSN
0020-1669 .
^ Ryazanov, M; Simon, A; Mattausch, Hj; Kremer, R.K (July 2004).
"The structural change of lanthanum diiodide upon hydrogenation" . Journal of Alloys and Compounds . 374 (1–2): 142–145.
doi :
10.1016/j.jallcom.2003.11.072 .
^
a
b Bochkarev, M. N.; Logunov, A. A.; Burin, M. E. (October 2007).
"Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H" . Russian Chemical Bulletin . 56 (10): 1953–1955.
doi :
10.1007/s11172-007-0303-x .
ISSN
1066-5285 .
S2CID
93943595 .
^
a
b Ruck, M.; Simon, A. (November 1992).
"Ln2XCHy: Kondensierte Cluster mit zwei verschiedenen interstitiellen Atomen" . Zeitschrift für anorganische und allgemeine Chemie (in German). 617 (11): 7–18.
doi :
10.1002/zaac.19926170102 .
ISSN
0044-2313 .
^
a
b Rudolph, Daniel; Wylezich, Thomas; Netzsch, Philip; Blaschkowski, Björn; Höppe, Henning A.; Goldner, Philippe; Kunkel, Nathalie; Hoslauer, Jean-Louis; Schleid, Thomas (2023-10-07).
"Synthesis and Crystal Structure of the Europium(II) Hydride Oxide Iodide Eu5H2O2I4 Showing Blue-Green Luminescence" . International Journal of Molecular Sciences . 24 (19): 14969.
doi :
10.3390/ijms241914969 .
ISSN
1422-0067 .
PMC
10573458 .
PMID
37834417 .
^ Oxley, Jimmie Carol (20 April 1978). Nitrosyl Hydrides and Cations of Group VI Transition Metals . California State University Northridge.
^ Bau, Robert; Drabnis, Mary H. (June 1997).
"Structures of transition metal hydrides determined by neutron diffraction" . Inorganica Chimica Acta . 259 (1–2): 27–50.
doi :
10.1016/S0020-1693(97)89125-6 .
^
a
b Eckert, Juergen; Jensen, Craig M.; Koetzle, Thomas F.; Husebo, Trang Le; Nicol, Jacqueline; Wu, Ping (July 1995). "Inelastic Neutron Scattering Studies of IrIH2(H2)(PPri3)2 and Neutron Diffraction Structure Determination of IrIH2(H2)(PPri3)2•C10H8: Implications on the Mechanism of the Interconversion of Dihydrogen and Hydride Ligands". Journal of the American Chemical Society . 117 (27): 7271–7272.
doi :
10.1021/ja00132a038 .
Salts and covalent derivatives of the
iodide ion