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The borate iodides are mixed anion compounds that contain both borate and iodide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate bromides.

List

name chem mw crystal system space group unit cell Å volume density comment references
Cr3B7O13I F4_3c a = 12.171 Z=8 18029 4.17 [1]
Mn3B7O13I F4_3c a = 12.32 Z=8 1870 4.09 [1]
Fe3B7O13I Pca21 a = 8.654, c = 12.2336 Z=4 915.57 4.19 [1]
Co3B7O13I F4_3c a = 12.119 Z=8 1779.9 4.38 [1]
Ni3B7O13I Pca21 a = 08.511 c = 12.037 Z=4 871.9 4.47 magnetoelectric, ferroelectric and ferroelastic [1]
Cu3B7O13I F4_3c a = 12.0203 Z=8 1736.8 4.60 [1]
Ag4B4O7I2 840.52 hexagonal P6122 a=8.9576 c=45.1956 Z=12 3140.6 5.33 [2]
tin iodide borate Sn3[B3O7]I orthorhombic Pbca a = 10.718, b = 8.523, and c = 20.168 Z = 8 [3]
La[B5O8(OH)(H2O)2I] 495.86 monoclinic P21/n a=6.529 b=15.494 c=10.744 β=90.353 Z=4 1086.8 3.03 colourless [4]
La[B7O11(OH)(H2O)3I] 581.48 orthorhombic P21/n a=8.178 b=17.251 c=9.849 Z=4 1389.4 2.78 colourless [5]
Ce[B5O8(OH)(H2O)2I] 497.07 monoclinic P21/n a= 6.498 b=15.416 c=10.704 β=90.306 Z=4 1072.3 3.079 colourless [4]
Ce[B7O11(OH)(H2O)3I] 582.69 orthorhombic P21/n a=8.1641 b=17.205 c=9.816 Z=4 1378.8 2.807 colourless [5]
Pr[B5O8(OH)(H2O)2I] 497.86 monoclinic P21/n a= 6.488 b=15.392 c=10.686 β=90.254 Z=4 1067.0 3.099 green [4]
Pr[B7O11(OH)(H2O)3I] 583.48 orthorhombic P21/n a=8.1504 b=17.205 c=9.814 Z=4 1376.2 2.816 light green [5]
Nd[B5O8(OH)(H2O)2I] 501.19 monoclinic P21/n a=6.4763 b=15.350 c=10.6734 β=90.316 Z=4 1061.0 3.137 purple [4]
Nd[B7O11(OH)(H2O)3I] 586.81 orthorhombic P21/n a=8.1464 b=17.199 c=9.735 Z=4 1372.2 2.841 purple [5]
Sm[B7O11(OH)(H2O)3I] 592.92 orthorhombic P21/n a=8.102 b=17.158 c=9.733 Z=4 1352.9 2.911 colourless [5]
dilead borate iodide Pb2BO3I trigonal P321 NLO 10 × KDP [6]
Pb2B5O9I 739.35 orthorhombic Pnm2 a=11.561 b=11.700 c=6.524 Z=4 882.5 5.565 colourless or yellow [7]
Pb6O4(BO3)I 1492.85 orthorhombic Pmmn a= 5.78 b=9.72 c=10.63 Z=2 597 8.302 colourless [8]
Pb10O4(BO3)3I3 2693.03 monoclinic Cc a=16.6423 b=9.0277 c=16.9746 β=115.658 Z=4 2298.8 7.781 colourless [9]
tetrabismuth borate tetraoxy iodide Bi4BO7I 1085.6 orthorhombic Immm a=3.959 b=13.453 c=3.969 Z=1 211.4 8.5279 dark orange [10]
Pu[B7O11(OH)(H2O)2I] 668.57 monoclinic P21/n a=8.110 b=17.060 c=9.792 β=90.133 Z=4 1354.9 3.278 pale blue [4]

References

  1. ^ a b c d e f Schnelle, Walter; Schmid, Hans (2015-05-20). "Magnetic and structural phase transitions of multiferroic boracites M 3 B 7 O 13 X ( M = 3 d transition metal Cr–Zn or Mg; X = halogen Cl , Br, I)". Physical Review B. 91 (18): 184411. Bibcode: 2015PhRvB..91r4411S. doi: 10.1103/PhysRevB.91.184411. ISSN  1098-0121.
  2. ^ Volkov, Sergey N.; Charkin, Dmitri O.; Arsent’ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V.; Bubnova, Rimma S. (2020-03-02). "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides". Inorganic Chemistry. 59 (5): 2655–2658. doi: 10.1021/acs.inorgchem.0c00306. ISSN  0020-1669. PMID  32049501. S2CID  211101969.
  3. ^ Schönegger, Sandra; Pielnhofer, Florian; Saxer, Andreas; Wurst, Klaus; Huppertz, Hubert (2019-05-06). "Synthesis and Characterization of the Tin Iodide Borate Sn 3 [B 3 O 7 ]I". Inorganic Chemistry. 58 (9): 6088–6094. doi: 10.1021/acs.inorgchem.9b00377. ISSN  0020-1669. PMID  30964677. S2CID  106408547.
  4. ^ a b c d e Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16). "Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates". Inorganic Chemistry. 51 (14): 7859–7866. doi: 10.1021/ic3009317. ISSN  0020-1669. PMID  22734798.
  5. ^ a b c d e Polinski, Matthew J.; Alekseev, Evgeny V.; Darling, Victoria R.; Cross, Justin N.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-02-18). "A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework". Inorganic Chemistry. 52 (4): 1965–1975. doi: 10.1021/ic302309z. ISSN  0020-1669. PMID  23360290.
  6. ^ Yu, Hongwei; Koocher, Nathan Z.; Rondinelli, James M.; Halasyamani, P. Shiv (2018-05-22). "Pb 2 BO 3 I: A Borate Iodide with the Largest Second-Harmonic Generation (SHG) Response in the KBe 2 BO 3 F 2 (KBBF) Family of Nonlinear Optical (NLO) Materials". Angewandte Chemie International Edition. 57 (21): 6100–6103. doi: 10.1002/anie.201802079. PMID  29512313.
  7. ^ Huang, Yi-Zhi; Wu, Li-Ming; Wu, Xin-Tao; Li, Long-Hua; Chen, Ling; Zhang, Yong-Fan (2010-09-22). "Pb 2 B 5 O 9 I: An Iodide Borate with Strong Second Harmonic Generation". Journal of the American Chemical Society. 132 (37): 12788–12789. doi: 10.1021/ja106066k. ISSN  0002-7863. PMID  20738133.
  8. ^ Li, Kuan; Yalikun, Alimujiang; Su, Zhi (2020). "[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains". Dalton Transactions. 49 (26): 8985–8990. doi: 10.1039/D0DT01722A. ISSN  1477-9226. PMID  32558837. S2CID  219924590.
  9. ^ Zhou, Jinjie; Wu, Hongping; Yu, Hongwei; Hu, Zhanggui; Wu, Yicheng (2019). "Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method". Dalton Transactions. 48 (40): 14996–15001. doi: 10.1039/C9DT02579K. ISSN  1477-9226. PMID  31369009. S2CID  199055810.
  10. ^ Volkov, Sergey; Bubnova, Rimma; Krzhizhanovskaya, Maria; Galafutnik, Lydia (2020-12-01). "The first bismuth borate oxyiodide, Bi 4 BO 7 I: commensurate or incommensurate?". Acta Crystallographica Section B. 76 (6): 992–1000. Bibcode: 2020AcCrB..76..992V. doi: 10.1107/S2052520620012640. ISSN  2052-5206. PMID  33289711. S2CID  227947646.
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