From Wikipedia, the free encyclopedia
Mixed anion compounds
The borate bromides are mixed anion compounds that contain
borate and
bromide
anions. They are in the borate halide family of compounds which also includes
borate fluorides,
borate chlorides, and
borate iodides.
List
name
|
chem
|
mw
|
crystal system
|
space group
|
unit cell Å
|
volume
|
density
|
comment
|
references
|
|
Li3B8O13Br
|
395.21
|
orthorhombic
|
Pca21
|
a 17.3967(5)Å b 9.4077(3)Å c 6.6750
|
1092.45
|
2.403
|
birefringence 0.088@1064 nm
|
[1]
|
|
Na3B4O7Br
|
|
hexagonal
|
P6522
|
a = 8.146 c = 20.24
|
1163.1
|
2.605
|
|
[2]
|
|
Na11B21O36Br2
|
1215.72
|
monoclinic
|
C2/c
|
a=15.722 b=8.951 c=24.087 β=100.728 Z=4
|
3330.3
|
2.425
|
|
[3]
|
KBOB
|
K3B6O10Br
|
422.07
|
trigonal
|
R3m
|
a=10.1153 c=8.8592 Z=3
|
785.02
|
2.678
|
colourless
|
[4]
|
|
K9[B4O5(OH)43(CO3)Br·7H2O
|
1191.75
|
hexagonal
|
P6_2c
|
a=11243 c=17.132 Z=2
|
1875
|
2.11
|
band gap 5.65 eV
|
[5]
|
|
Zn2BO3Br·H2O
|
287.48
|
orthorhombic
|
P212121
|
a=4.962 b=8.484 c=14.644 Z=4
|
616.5
|
3.097
|
NLO 0.6x KDP
|
[6]
|
|
KZn2BO3Br2
|
345.92
|
trigonal
|
R32
|
a=4.9611 c=27.221 Z=3
|
580.2
|
2.970
|
white
|
[7]
|
|
RbZn2BO3Br2
|
388.47
|
trigonal
|
R32
|
a=4.9618 c=28.199 Z=3
|
601.2
|
3.219
|
white
|
[7]
|
|
Ag4B4O7Br2
|
746.52
|
hexagonal
|
P6122
|
a=8.8291 c=44.7416 Z=12
|
3020.5
|
4.92
|
|
[8]
|
|
Sn2B5O9Br
|
515.34
|
orthorhombic
|
Pnn2
|
a = 11.398 b = 11.446 c = 6.553 Z=4
|
854.9
|
4.004
|
birefringence=0.439 at 546 nm; SHG 4.8x; white
|
[9]
|
|
NaBa4(GaB4O9)2Br3
|
1326.00
|
tetragonal
|
P42nm
|
a=12.33 c=6.91 Z=2
|
1053
|
4.18
|
NLO 1.1x KDP
|
[10]
|
|
La[B5O8(OH)(H2O)2Br]
|
448.87
|
monoclinic
|
P21/n
|
a=6.520 b=15.213 c=10.704 β=90.017 Z=4
|
1061.6
|
2.808
|
colourless
|
[11]
|
LaBOBr
|
La[B7O10(OH)3(H2O)Br]
|
518.49
|
monoclinic
|
P21/n
|
a=7.944 b=15.105 c=9.836 β=90 Z=4
|
1180.3
|
2.918
|
|
[12]
|
|
Ce[B5O8(OH)(H2O)2Br]
|
450.08
|
monoclinic
|
P21/n
|
a=6.495 b=15.159 c=10.670 β=90.048 Z=4
|
1050.6
|
2.846
|
colourless
|
[11]
|
CeBOBr
|
Ce[B6O9(OH)2(H2O)2Br]·0.5H2O
|
500.89
|
monoclinic
|
P21/n
|
a=8.1507 b=14.874 c=9.867 β=90.085 Z=4
|
1196.3
|
2.781
|
|
[12]
|
PrBOBr
|
Pr[B6O9(OH)2(H2O)2Br]·0.5H2O
|
501.68
|
monoclinic
|
P21/n
|
a=8.1346 b=14.819 c=9.847 β=90.153 Z=4
|
1187.0
|
2.807
|
green
|
[12]
|
|
Pr[B5O8(OH)(H2O)2Br]
|
450.87
|
monoclinic
|
P21/n
|
a=6.4910 b=15.143 c=10.664 β=90.0440 Z=4
|
1048.2
|
2.857
|
|
[11]
|
NdBOBr
|
Nd2[B12O17.5(OH)5(H2O)4Br1.5]Br0.5·H2O
|
1018.02
|
orthorhombic
|
Fdd2
|
a=30.6641 b=19.7946 c=16.0737 Z=16
|
9757.3
|
2.772
|
purple
|
[12]
|
|
Nd4[B18O25(OH)13Br3]
|
1619.27
|
monoclinic
|
P2/c
|
a=10.544 b=6.451 c=23.485 β=97.754 Z=2
|
1583
|
3.397
|
purple
|
[11]
|
SmBOBr
|
Sm4[B18O25(OH)13Br3]
|
1643.71
|
monoclinic
|
P21/n
|
a=10.508 b=6.427 c=23.408 β=97.585 Z=2
|
1567
|
3.484
|
|
[12]
|
|
Ba2BO3Br
|
|
|
P-3m1
|
a = 5.516, c = 11.019, and Z = 2
|
|
|
|
[13]
|
|
Ba3BO3Br3
|
|
triclinic
|
P-1
|
a = 9.280, b = 9.349 c = 13.025, α = 92.71°, β = 98.29°, γ = 116.20° and Z = 4
|
|
|
|
[13]
|
|
Ba7(BO3)3SiO4Br
|
|
orthorhombic
|
P63mc
|
|
|
|
|
[14]
|
|
Ba7(BO3)3GeO4Br
|
1354.31
|
orthorhombic
|
Pbam
|
a=20.381 b=7.477 c=11.175 Z=4
|
1702.9
|
5.283
|
|
[14]
|
|
Pb2Ba3(BO3)3Br
|
1082.74
|
orthorhombic
|
C2221
|
a=10.538 b=14.2878 c=8.107 Z=4
|
1220.7
|
5.891
|
NLO 3.1×KDP; colourless
|
[15]
|
References
-
^ Hu, Mei; Tuerhong, Nuerbiye; Chen, Zhaohui; Jing, Qun; Lee, Ming-Hsien (2023-02-16).
"Li 3 B 8 O 13 X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO 3 Units". Inorganic Chemistry. 62 (8): 3609–3615.
doi:
10.1021/acs.inorgchem.2c04376.
ISSN
0020-1669.
PMID
36795025.
S2CID
256899976.
-
^ Bai, Chunyan; Han, Shujuan; Pan, Shilie; Zhang, Bingbing; Yang, Yun; Li, Lin; Yang, Zhihua (2015).
"Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra". RSC Advances. 5 (16): 12416–12422.
Bibcode:
2015RSCAd...512416B.
doi:
10.1039/C4RA16639F.
ISSN
2046-2069.
-
^ Dong, Xiaoyu; Wu, Hongping; Shi, Yunjing; Yu, Hongwei; Yang, Zhihua; Zhang, Bingbing; Chen, Zhaohui; Yang, Yun; Huang, Zhenjun; Pan, Shilie; Zhou, Zhongxiang (2013-06-03).
"Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene-Like Borate Double Layer". Chemistry - A European Journal. 19 (23): 7338–7341.
doi:
10.1002/chem.201300902.
PMID
23630069.
-
^ Zhang, Min; Su, Xin; Pan, Shilie; Wang, Zheng; Zhang, Hui; Yang, Zhihua; Zhang, Bingbing; Dong, Lingyun; Wang, Ying; Zhang, Fangfang; Yang, Yun (2014-06-05).
"Linear and Nonlinear Optical Properties of K 3 B 6 O 10 Br Single Crystal: Experiment and Calculation". The Journal of Physical Chemistry C. 118 (22): 11849–11856.
doi:
10.1021/jp500858q.
ISSN
1932-7447.
-
^ Zhang, Xueyan; Wu, Hongping; Cheng, Shichao; Han, Guopeng; Yang, Zhihua; Pan, Shilie (2019-05-20).
"K 9 [B 4 O 5 (OH) 4 ] 3 (CO 3 )X·7H 2 O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges". Inorganic Chemistry. 58 (10): 6974–6982.
doi:
10.1021/acs.inorgchem.9b00593.
ISSN
0020-1669.
PMID
31042371.
S2CID
143422681.
-
^ Song, Yunxia; Yang, Guangsai; Gong, Pifu; Luo, Min; Lin, Zheshuai; Ye, Ning (2020-06-01).
"Hydrogen-Bond-Assisted Reinforcement of Interlayer Connections in Zn 2 BO 3 X·H 2 O (X = Cl, Br): Two UV Nonlinear Optical Crystals with KBBF-Type Structure". Inorganic Chemistry. 59 (11): 7789–7794.
doi:
10.1021/acs.inorgchem.0c00874.
ISSN
0020-1669.
PMID
32401026.
S2CID
218618490.
- ^
a
b Yang, Guangsai; Gong, Pifu; Lin, Zheshuai; Ye, Ning (2016-12-27).
"AZn 2 BO 3 X 2 (A = K, Rb, NH 4 ; X = Cl, Br): New Members of KBBF Family Exhibiting Large SHG Response and the Enhancement of Layer Interaction by Modified Structures". Chemistry of Materials. 28 (24): 9122–9131.
doi:
10.1021/acs.chemmater.6b04272.
ISSN
0897-4756.
-
^ Volkov, Sergey N.; Charkin, Dmitri O.; Arsent’ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V.; Bubnova, Rimma S. (2020-03-02).
"Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides". Inorganic Chemistry. 59 (5): 2655–2658.
doi:
10.1021/acs.inorgchem.0c00306.
ISSN
0020-1669.
PMID
32049501.
S2CID
211101969.
-
^ Guo, Jingyu; Cheng, Shichao; Han, Shujuan; Yang, Zhihua; Pan, Shilie (March 2021).
"Sn 2 B 5 O 9 Br as an Outstanding Bifunctional Material with Strong Second-Harmonic Generation Effect and Large Birefringence". Advanced Optical Materials. 9 (5): 2001734.
doi:
10.1002/adom.202001734.
ISSN
2195-1071.
S2CID
230528677.
-
^ Wen, Ming; Su, Xin; Wu, Hongping; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2016-03-24).
"NaBa 4 (GaB 4 O 9 ) 2 X 3 (X = Cl, Br) with NLO-Active GaO 4 Tetrahedral Unit: Experimental and ab Initio Studies". The Journal of Physical Chemistry C. 120 (11): 6190–6197.
doi:
10.1021/acs.jpcc.6b00265.
ISSN
1932-7447.
- ^
a
b
c
d Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16).
"Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates". Inorganic Chemistry. 51 (14): 7859–7866.
doi:
10.1021/ic3009317.
ISSN
0020-1669.
PMID
22734798.
- ^
a
b
c
d
e Polinski, Matthew J.; Alekseev, Evgeny V.; Darling, Victoria R.; Cross, Justin N.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-02-18).
"A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework". Inorganic Chemistry. 52 (4): 1965–1975.
doi:
10.1021/ic302309z.
ISSN
0020-1669.
PMID
23360290.
- ^
a
b Zhao, Jing; Li, R.K. (October 2013).
"Two new barium borate bromides: Ba2BO3Br and Ba3BO3Br3". Solid State Sciences. 24: 54–57.
Bibcode:
2013SSSci..24...54Z.
doi:
10.1016/j.solidstatesciences.2013.07.009.
- ^
a
b Wen, Ming; Lian, Zhipeng; Wu, Hongping; Su, Xin; Yan, Qingfeng; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2015).
"Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra". RSC Advances. 5 (66): 53448–53454.
Bibcode:
2015RSCAd...553448W.
doi:
10.1039/C5RA07450A.
ISSN
2046-2069.
-
^ Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie (2015).
"Synthesis and optical properties of the first lead borate bromide with isolated BO 3 groups: Pb 2 Ba 3 (BO 3 ) 3 Br". Dalton Transactions. 44 (38): 16818–16823.
doi:
10.1039/C5DT02652K.
ISSN
1477-9226.
PMID
26347088.
Salts and covalent derivatives of the
bromide ion |
---|
|