From Wikipedia, the free encyclopedia
Borate sulfides are chemical
mixed anion compounds that contain any kind of
borate and
sulfide ions. They are distinct from
thioborates in which sulfur atoms replace oxygen in borates. There are also analogous
borate selenides , with selenium ions instead of sulfur.
List
name
chem
mw
crystal system
space group
unit cell
volume
density
comments
references
Zn4 B6 O12 S
I 4 3m
NLO 1.9 × KDP
[1]
cadmium sulfur boracite
Cd3 B7 O13 S2
cubic
F 4 3c
[2]
La6 Nb2 MgSB8 O26
trigonal
P 3
a=8.2137 c =8.8601
clear
[3]
Ce6 Nb2 MgSB8 O26
trigonal
P 3
a=8.1672 c =8.8093
clear
[3]
Pr6 Nb2 MgSB8 O26
trigonal
P 3
a=8.1362 c =8.7716
yellowish green
[3]
Nd6 Nb2 MgSB8 O26
trigonal
P 3
a=8.1135 c =8.7469
clear
[3]
EBOS
Eu2 B5 O9 S
534.03
orthorhombic
Pnn 2
a=11.2909 b=11.3742 c=6.4440 Z=4
827.57
4.286
black
[4]
EBOSI
Eu4.5 (B5 O9 )2 SI
1238.88
orthorhombic
Pnn 2
a=11.529 b=11.550 c=6.5070 Z=2
866.5
4.748
yellow-green band gap 1.98 eV
[4]
EMSBO
Eu9 MgS2 B20 O41
2328.27
Hexagonal
P 63 /m
a=8.2708 c=24.919 Z=2
1476.3
5.238
brown
[5]
Eu6 Ta2 MgSB8 O26
1832.51
trigonal
P 3
a=8.0431 c=8.6486 Z=1
484.53
6.280
[6]
Sm3 S3 BO3
606.04
triclinic
P 1
a=4.0173 b=7.647 c=11.241 α=91.339 β =91.275 γ =90.349 Z=2
345.14
5.832
green; band gap 2.5 eV
[7]
Gd3 S3 BO3
626.74
triclinic
P 1
a=3.9725 b=7.5945 c=11.182 α=91.402 β =91.093 γ =90.206 Z=2
337.30
6.173
pale yellow; band gap 2.65 eV
[8]
References
^ Zhou, Wenfeng; Yao, Wen-Dong; Tang, Ru-Ling; Xue, Huaiguo; Guo, Sheng-Ping (2021-06-25).
"Second-order nonlinear optical and photoelectric properties of Zn4B6O12S" . Journal of Alloys and Compounds . 867 : 158879.
doi :
10.1016/j.jallcom.2021.158879 .
ISSN
0925-8388 .
S2CID
233544941 .
^ Gould, R O; Nelmes, R J; Gould, S E B (1981-12-10).
"Structural studies of boracites. VII. Cadmium sulphur boracite at room temperature" . Journal of Physics C: Solid State Physics . 14 (34): 5259–5267.
Bibcode :
1981JPhC...14.5259G .
doi :
10.1088/0022-3719/14/34/008 .
ISSN
0022-3719 .
^
a
b
c
d Tang, Ru-Ling; Wei, Yu-Long; Chi, Yang; Shi, Zhi-Hui; Liu, Wenlong; Guo, Sheng-Ping (2022-06-13).
"Cation Regulation to Investigate the Chalcogenide Borate RE 6 Nb 2 MgSB 8 O 26 (RE = La–Nd) Family" . Inorganic Chemistry . 61 (23): 8653–8661.
doi :
10.1021/acs.inorgchem.2c00033 .
ISSN
0020-1669 .
PMID
35622004 .
S2CID
249095609 .
^
a
b Chi, Yang; Xue, Huai-Guo; Guo, Sheng-Ping (2020-01-21).
"Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material" . Inorganic Chemistry . 59 (2): 1547–1555.
doi :
10.1021/acs.inorgchem.9b03426 .
ISSN
0020-1669 .
PMID
31909601 .
S2CID
210043683 .
^ Chi, Yang; Xu, Jing; Xue, Huai-Guo; Zhang, Yueping; Chen, Xiaolong; Whangbo, Myung-Hwan; Guo, Sheng-Ping; Deng, Shuiquan (2019-06-19).
"Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu9MgS2B20O41" . Journal of the American Chemical Society . 141 (24): 9533–9536.
doi :
10.1021/jacs.9b04627 .
ISSN
0002-7863 .
PMID
31184141 .
S2CID
184485492 .
^ Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16).
"A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster" . Inorganic Chemistry . 59 (6): 3532–3536.
doi :
10.1021/acs.inorgchem.0c00086 .
ISSN
0020-1669 .
PMID
32090554 .
S2CID
211263182 .
^ Guo, Sheng-Ping; Chi, Yang; Xue, Huai-Guo (2015-12-07).
"Sm 3 S 3 BO 3 : The First Sulfide Borate without S–O and B–S Bonds" . Inorganic Chemistry . 54 (23): 11052–11054.
doi :
10.1021/acs.inorgchem.5b01930 .
ISSN
0020-1669 .
PMID
26558599 .
^ Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01).
"Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)" . New Journal of Chemistry . 40 (8): 6720–6727.
doi :
10.1039/C6NJ00549G .
ISSN
1369-9261 .