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Arsenide chlorides or chloride arsenides are compounds containing anions composed of chloride (Cl− ) and arsenide (As3− ). They can be considered as
mixed anion compounds . They are in the category of
pnictidehalides . Related compounds include the
arsenide bromides ,
arsenide iodides ,
phosphide chlorides , and
antimonide chlorides .
List
formula
system
space group
unit cell Å
volume
density
comment
ref
Ca3 AsCl3
Pm 3m
a= 5.760
[1]
Sr2 AsCl
dark violet
[2]
Cd8 As7 Cl
cubic
P 23
a =7.266, Z =1
[3]
Hg7.4 As4 Cl6
cubic
Pa 3
a = 12.178, Z = 4
[4]
(Hg6 As4 )(HgCl6 )Hg0.5
cubic
Pa 3
a=12.189 Z=4
1810.7
7.398
yellow; air stable; band gap 2.01
[5]
(Hg6 As4 )[TiCl6 ]Cl
cubic
Pa 3
a = 1209.4
[6]
[Hg4 As2 ][ZrCl6 ]
orthorhombic
Pbca
a=13.277 b=13.420 c=16.814 Z=8
2769.1
5.570
dark yellow
[7]
[Hg4 As2 ][HfCl6 ]
orthorhombic
Pbca
a=13.273 b=13.413 c=16.809 Z=8
2992
5.964
orange
[7]
(Hg3 AsS)(GaCl4 )
hexagonal
P 63 /mc
a =7.245, c =11.960 , Z = 2
543.6
5.622
light yellow
[8]
Hg3 AsS4 Cl
hexagonal
P 63 mc
a = 7.431, c = 9.003 Z=2
yellow; air stable
[9]
[Hg6 As4 ](CuCl3 )2
monoclinic
I 2/a
a = 14.690, b = 9.1851, c = 20.285, β=92.170, Z=6
[10]
(Hg9.75 As5.5 )(GaCl4 )3
orthorhombic
Pmn 21
a=22.567 b=12.146 c=12.983 Z=4
3559
5.604
[11]
(Hg6 As4 )[MoCl6 ]Cl
cubic
Pa 3
a = 12.078
[6]
[Hg6 As4 ](AgCl3 )2
monoclinic
I 2/a
a = 14.690, b = 9.1851, c = 20.285, β = 93.17°, Z = 4
[10]
[12]
(Hg6 As4 )(CdCl6 )Hg0.5
cubic
Pa 3
a=12.172 Z=4
1803.2
7.104
yellow; air stable; band gap 2.05
[5]
[Hg6 As4 ](InCl6 )Cl
cubic
Pa 3
a = 12.109, Z = 4
dark red
[13]
[Hg6 As4 Cl3 ](SnCl3 )Hg0.13
cubic
P 21 3
a=12.233 Z=4
[14]
Hg3 As2 TlCl3
orthorhombic
Pbcm
a = 6.292, b = 12.341 c = 12.248 Z=4
red
[15]
Hg6 As4 BiCl7
cubic
Pa 3
a =12.178 Z=4
[16]
[Hg4 As2 ][UCl6 ]
orthorhombic
Pbca
a=13.316 b=13.636 c=16.853 Z=8
3060.0
6.090
red
[7]
[17]
References
^ Hadenfeldt, C.; Vollert, H. O. (August 1982).
"Darstellung, thermisches Verhalten und Kristallstruktur des Calciumarsenidchlorids Ca3AsCl3" . Zeitschrift für anorganische und allgemeine Chemie (in German). 491 (1): 113–118.
doi :
10.1002/zaac.19824910115 .
ISSN
0044-2313 .
^ Hadenfeldt, Claus (1976-04-01).
"Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3" . Zeitschrift für Naturforschung B . 31 (4): 408–410.
doi :
10.1515/znb-1976-0403 .
ISSN
1865-7117 .
S2CID
95122668 .
^ Shevelkov, Andrei V.; Reshetova, Ludmila N.; Popovkin, Boris A. (December 1997).
"Cd8As7Cl: A Novel Pnictidohalide with a New Structure Type" . Journal of Solid State Chemistry . 134 (2): 282–285.
Bibcode :
1997JSSCh.134..282S .
doi :
10.1006/jssc.1997.7555 .
^ Shevelkov, Andrei V.; Dikarev, Evgeny V.; Popovkin, Boris A. (November 1996).
"Two New Cubic Structures of Mercury Arsenidehalides" . Journal of Solid State Chemistry . 126 (2): 324–327.
Bibcode :
1996JSSCh.126..324S .
doi :
10.1006/jssc.1996.0344 .
^
a
b Zou, Jian-Ping; Li, Yan; Fu, Ming-Lai; Guo, Guo-Cong; Xu, Gang; Liu, Xue-Hui; Zhou, Wei-Wei; Huang, Jin-Shun (March 2007).
"The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)" . European Journal of Inorganic Chemistry . 2007 (7): 977–984.
doi :
10.1002/ejic.200600894 .
ISSN
1434-1948 .
^
a
b Beck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br". Zeitschrift für Anorganische und Allgemeine Chemie . 626 (7): 1620–1626.
doi :
10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R .
^
a
b
c Li, Xiao-Guo; Jiang, Xiao-Ming; Zhang, Ming-Jian; Liu, Bin-Wen; Fan, Yu-Hang; Guo, Guo-Cong; Huang, Jin-Shun (2013-12-02).
"Three-Dimensional Mercury Pnictide [Hg 4 Z 2 ] 2+ Cationic Frameworks Stabilized by Tetravalent Metal Halide Anions in Supramolecular Complexes: [Hg 4 Z 2 ][MCl 6 ] (Z = P, As; M = Zr, Hf)" . European Journal of Inorganic Chemistry . 2013 (35): 5980–5986.
doi :
10.1002/ejic.201300888 .
ISSN
1434-1948 .
^ Jiang, Xiao-Ming; Li, Xiao-Guo; Fan, Yu-Hang; Liu, Bin-Wen; Zeng, Hui-Yi; Guo, Guo-Cong (2013).
"New mercury-contained cationic frameworks stabilized by (GaCl4)− unit via weak electrostatic forces in supramolecular compounds (Hg11P4)(GaCl4)4 and (Hg3AsS)(GaCl4)" . Dalton Transactions . 42 (43): 15475–15481.
doi :
10.1039/c3dt51451j .
ISSN
1477-9226 .
PMID
24022795 .
^ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01).
"Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure" . Inorganic Chemistry . 39 (25): 5847–5850.
doi :
10.1021/ic0003527 .
ISSN
0020-1669 .
PMID
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^
a
b Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005).
"Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework" . Journal of Cluster Science . 16 (2): 273–285.
doi :
10.1007/s10876-005-4548-y .
ISSN
1040-7278 .
S2CID
95453360 .
^ Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Ke-Feng; Guo, Guo-Cong; Li, Shao-Zhen; Liu, Jun-Ming (October 2014).
"Large and Fast Single-Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host-Guest Interactions" . Chemistry: An Asian Journal . 9 (10): 2872–2879.
doi :
10.1002/asia.201402572 .
PMID
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^ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (October 2004).
"From Discrete to Extended Guests: A Novel Supramolecular [Hg 6 As 4 ](AgCl 3 ) 2 Assembly Featuring One-Dimensional (AgCl 3 ) 2− Anions" . European Journal of Inorganic Chemistry . 2004 (20): 4006–4010.
doi :
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ISSN
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^ Olenev, A. V.; Baranov, A. I.; Shatruk, M. M.; Tyablikov, A. S.; Shevelkov, A. V. (2002).
"Synthesis and the crystal structure of [Hg6 As4] (InCl6 )Cl: influence of covalent and electrostatic factors on the supramolecular structure" . Russian Chemical Bulletin . 51 (3): 444–448.
doi :
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S2CID
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^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry . 2002 (3): 547–553.
doi :
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^ Beck, Johannes; Neisel, Udo (2001). "Polykationische Hg-Pnictid-Gerüste mit einer neuen Füllungsvariante in den Strukturen von Hg3As2TlCl3 und Hg3Sb2TlBr3". Zeitschrift für Anorganische und Allgemeine Chemie . 627 (8): 2016–2022.
doi :
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^ Beck, Johannes; Hedderich, Sylvia; Neisel, Udo (November 2000).
"Synthesis and Crystal Structures of Hg6Sb5Br7, Hg6As4BiCl7, and Hg6Sb4BiBr7, Built of a Polycationic Mercury-Pnictide Framework with Trapped Anions" . Journal of Solid State Chemistry . 154 (2): 350–355.
Bibcode :
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doi :
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^ Bugaris, Daniel E.; Ibers, James A. (December 2008).
"Syntheses, structures, and magnetic and optical properties of the compounds [Hg3Te2][UCl6] and [Hg4As2][UCl6]" . Journal of Solid State Chemistry . 181 (12): 3189–3193.
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Salts and covalent derivatives of the
chloride ion