| Identifiers | |
|---|---|
3D model (
JSmol)
|
|
| |
| |
| Properties | |
| BiAs | |
| Molar mass | 283.9 |
| Appearance | solid |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Bismuth arsenide is an inorganic compound, with the chemical formula BiAs. Its α-modification [1] and β-modification [2] have been reported in theoretical calculations.
Preparation
Bismuth arsenide can be prepared by reacting bismuth chloride and tris(trimethylsilyl)arsenic in toluene at room temperature: [3]
- BiCl3 + As[Si(CH3)33 → BiAs + 3(CH3)3SiCl
References
-
^ Wen-Zhi Xiao, Gang Xiao, Qing-Yan Rong, Ling-Ling Wang (2018-03-07).
"New two-dimensional V-V binary compounds with a honeycomb-like structure: a first-principles study". Materials Research Express. 5 (3): 035903.
Bibcode:
2018MRE.....5c5903X.
doi:
10.1088/2053-1591/aab06c.
ISSN
2053-1591.
S2CID
103580668. Retrieved 2020-04-25.
{{ cite journal}}: CS1 maint: multiple names: authors list ( link) -
^ C. Y. Wu, L. Sun, J. C. Han, H. R. Gong (2020).
"Band structure, phonon spectrum, and thermoelectric properties of β-BiAs and β-BiSb monolayers". Journal of Materials Chemistry C. 8 (2): 581–590.
doi:
10.1039/C9TC04842A.
ISSN
2050-7526.
S2CID
213271946. Retrieved 2020-04-25.
{{ cite journal}}: CS1 maint: multiple names: authors list ( link) -
^ Geoff C. Allen, Claire J. Carmalt, Alan H. Cowley, Andrew L. Hector, Smuruthi Kamepalli, Yvonne G. Lawson, Nicholas C. Norman, Ivan P. Parkin, Laura K. Pickard (Jun 1997).
"Preparation and Characterization of a Material of Composition BiP (Bismuth Phosphide) and Other Intergroup 15 Element Phases". Chemistry of Materials. 9 (6): 1385–1392.
doi:
10.1021/cm960606f.
ISSN
0897-4756.
Archived from the original on 2022-01-17. Retrieved 2020-04-25.
{{ cite journal}}: CS1 maint: multiple names: authors list ( link)