From Wikipedia, the free encyclopedia
Lithium hexafluorotitanate
Names
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Other names
dilithium hexafluorotitanate, titanium lithium hexafluoride
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Identifiers
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ChemSpider
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EC Number
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InChI=1S/6FH-C.2Li.Ti/h6*1H;;;/q;;;;;;2*+1;+4/p-6 Key: AHARGQJTTQNBPT-UHFFFAOYSA-H
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[Li+].[Li+].F[Ti-2](F)(F)(F)(F)F
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Properties
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F6Li2Ti
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Molar mass
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175.74 g·mol−1
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Appearance
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solid
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Density
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2.89 g/cm3
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Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Lithium hexafluorotitanate is an
inorganic compound of
lithium,
fluorine, and
titanium with the chemical formula Li2TiF6.
[1]
[2]
Synthesis
Interaction of
titanium hydroxide or oxide and
lithium fluoride with
hydrofluoric acid.
[3]
Physical properties
The compound forms crystals of
tetragonal crystal system with a
space group of P42/mnm (no. 136).
[4]
Chemical properties
The compound forms hydrates Li3TiF6*xH2O.
[5]
[6]
References
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^
"Lithium Hexafluorotitanate". American Elements.
American Elements. Retrieved 16 February 2024.
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^
"LITHIUM HEXAFLUOROTITANATE". chemsrc.com. Retrieved 16 February 2024.
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^ Tikhomirova, E. L.; Nesterov, D. P.; Gromov, O. G.; Lokshin, E. P.; Kalinnikov, V. T. (1 June 2013).
"Synthesis of lithium hexafluorotitanate". Russian Journal of Applied Chemistry. 86 (6): 831–835.
doi:
10.1134/S1070427213060074.
ISSN
1608-3296.
S2CID
97687706. Retrieved 16 February 2024.
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^
"mp-7603".
Materials Project. Retrieved 16 February 2024.
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^ Marseglia, E. A.; Brown, I. D. (15 June 1973).
"Lithium hexafluorotitanate dihydrate and lithium hexafluorostannate dihydrate".
Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 29 (6): 1352–1354.
Bibcode:
1973AcCrB..29.1352M.
doi:
10.1107/S0567740873004498.
ISSN
0567-7408. Retrieved 16 February 2024.
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^ Nyquist, Richard A.; Putzig, Curtis L.; Kagel, Ronald O.; Leugers, M. Anne (28 December 1971).
Handbook of Infrared and Raman Spectra of Inorganic Compounds and Organic Salts: Infrared Spectra of Inorganic Compounds.
Academic Press. p. 32.
ISBN
978-0-12-523450-4. Retrieved 16 February 2024.
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Titanium(II) | Organotitanium(II) compounds | |
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Titanium(III) | Organotitanium(III) compounds | |
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Titanium(IV) | Titanate compounds | |
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Organotitanium(IV) compounds | |
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PF6−, AsF6−, SbF6− compounds | |
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AlF6− compounds | |
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chlorides, bromides, iodides and pseudohalogenides | |
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SiF62-, GeF62- compounds | |
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Oxyfluorides | |
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Organofluorides | |
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with transition metal, lanthanide, actinide, ammonium | |
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nitric acids | |
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bifluorides | |
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thionyl, phosphoryl, and iodosyl | |
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