From Wikipedia, the free encyclopedia
Pertechnetyl fluoride
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Identifiers
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InChI=1S/FH.3O.Tc/h1H;;;;/q;;;;+1/p-1 Key: OYCMXSPACZPBDD-UHFFFAOYSA-M
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Properties
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TcO 3F
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Molar mass
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165,00 g/mol
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Appearance
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yellow substance
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Melting point
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18.3 °C (64.9 °F; 291.4 K)
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Boiling point
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100 °C (212 °F; 373 K)
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insoluble
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Related compounds
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Related compounds
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Lanthanum oxyfluoride
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Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Pertechnetyl fluoride is an
inorganic compound, a salt of
technetium and
hydrofluoric acid with the chemical formula TcO
3F. The compound was originally synthesized by H. Selig and G. Malm in 1963.
[1]
[2]
Synthesis
Physical properties
The compound forms a yellow substance.
[4]
Chemical properties
The compound can be hydrolyzed to produce
pertechnetic acid and
hydrofluoric acid.
It also reacts with
arsenic pentafluoride or
antimony pentafluoride.
[5]
References
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^ Schmidbaur, Hubert; Schwarz, W. H. Eugen (21 April 2021).
"Permanganyl Fluoride: A Brief History of the Molecule MnO 3 F and of Those Who Cared For It".
Chemistry – A European Journal. 27 (23): 6848–6859.
doi:
10.1002/chem.202004759.
ISSN
0947-6539.
PMC
8247864.
PMID
33219726.
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^ Baran, Enrique J. (1 January 1975).
"Vibrational Properties of Pertechnetyl Fluoride".
Spectroscopy Letters. 8 (8): 599–603.
doi:
10.1080/00387017508067365.
ISSN
0038-7010. Retrieved 22 March 2023.
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^ Selig, H.; Malm, J. G. (1 April 1963).
"The preparation and properties of pertechnetyl fluoride, TcO3F".
Journal of Inorganic and Nuclear Chemistry. 25 (4): 349–351.
doi:
10.1016/0022-1902(63)80183-9.
ISSN
0022-1902. Retrieved 22 March 2023.
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^ Lawroski, Stephen (1963).
"Research and development on nonaqueous processing". Reactor Fuel Processing. 7 (1). U.S. Argonne National Laboratory.: 28. Retrieved 22 March 2023.
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^ Supeł, Joanna; Abram, Ulrich; Hagenbach, Adelheid; Seppelt, Konrad (1 July 2007).
"Technetium Fluoride Trioxide, TcO 3 F, Preparation and Properties".
Inorganic Chemistry. 46 (14): 5591–5595.
doi:
10.1021/ic070333y.
ISSN
0020-1669.
PMID
17547395. Retrieved 22 March 2023.
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Technetium(II) | |
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Technetium(III) | |
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Technetium(IV) | |
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Technetium(V) | |
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Technetium(VI) | |
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Technetium(VII) | |
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PF6−, AsF6−, SbF6− compounds | |
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AlF6− compounds | |
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chlorides, bromides, iodides and pseudohalogenides | |
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SiF62-, GeF62- compounds | |
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Oxyfluorides | |
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Organofluorides | |
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with transition metal, lanthanide, actinide, ammonium | |
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nitric acids | |
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bifluorides | |
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thionyl, phosphoryl, and iodosyl | |
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