From Wikipedia, the free encyclopedia
Zirconium phosphide
Names
IUPAC name
Phosphinidinzirconium
Identifiers
ChemSpider
EC Number
InChI=1S/P.Zr
Key: VQYKQHDWCVUGBB-UHFFFAOYSA-N
Properties
P Zr
Molar mass
122.198 g·mol−1
Appearance
solid
Hazards
GHS labelling :
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Zirconium monophosphide is a binary
inorganic compound of
zirconium metal and
phosphorus with the chemical formula ZrP .
[1]
[2]
[3]
Preparation
Zirconium monophosphide can be prepared from direct reaction of zirconium powders with
red phosphorus :
[4]
4 Zr + P4 → 4 ZrP
Physical properties
The α -form of zirconium monophosphide has a
NaCl crystal structure.
[5] The β -form structure is hexagonal. The α -form is a superconductor if cooled below 5K.
[6]
References
^
"Zirconium Phosphide" .
American Elements . Retrieved 7 March 2024 .
^ Irani, K. S.; Gingerich, K. A. (1 October 1963).
"Structural transformation of zirconium phosphide" .
Journal of Physics and Chemistry of Solids . 24 (10): 1153–1158.
doi :
10.1016/0022-3697(63)90231-2 .
ISSN
0022-3697 . Retrieved 7 March 2024 .
^ O'Bannon, Loran (6 December 2012).
Dictionary of Ceramic Science and Engineering .
Springer Science & Business Media . p. 283.
ISBN
978-1-4613-2655-7 . Retrieved 7 March 2024 .
^ Li, Zhen; Chen, Ning; Wang, Jigang; Li, Peishen; Guo, Ming; Wang, Qiang; Li, Chunhong; Wang, Changzheng; Guo, Tao; Chen, Shaowei (12 October 2017).
"Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method" (PDF) .
Scientific Reports . 7 (1).
doi :
10.1038/s41598-017-13616-5 .
^ Swanson, Howard Eugene (1962).
Standard X-ray Diffraction Powder Patterns: Data for 46 substances .
National Bureau of Standards . p. 75. Retrieved 7 March 2024 .
^ Macintyre, Jane E. (23 July 1992).
Dictionary of Inorganic Compounds .
CRC Press . p. 3769.
ISBN
978-0-412-30120-9 . Retrieved 7 March 2024 .
Zr(II) Zr(III) Zr(IV) Acids and complexes Organozirconium(IV)