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Class of chemical compounds
Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br− ) and phosphide (P3− ) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as
mixed anion compounds . They are in the category of
pnictidehalides . Related compounds include the
phosphide chlorides ,
phosphide iodides ,
nitride bromides ,
arsenide bromides , and
antimonide bromides .
List
formula
system
space group
unit cell Å
volume
density
comment
ref
Ca2 PBr
cubic
I 4 3d
a=5.96 Z=2
red brown
[1]
Ca2 PBr
hexagonal
R 3 m
a=4.23 c=20.9 Z=3
[1]
Cu12 P20 Br10
triclinic
P
a = 9.886, b = 13.190, c = 14.763, α = 70.83°, β = 82.68°, γ = 80.13°, Z = 2
1786.1
[2]
Cu13 P15 Br12
[3]
Cu6 PS5 Br
cubic
P 4 3m
a=9.732 Z=4
921.8
4.701
red
[4]
(CuBr)2 P8 Se3
orthorhombic
Pbcm
a=8.761 b=11.957 c=13.858 Z=4
1451.8
[5]
Sr2 PBr
cubic
I 4 3d
a=9.31 Z=2
brown violet
[1]
Sr2 PBr
hexagonal
R 3 m
a=4.44 c=22.0 Z=3
dark reddish brown
[1]
Sr2 P7 Br
cubic
P 21 3
a=9.789 Z=4
938.0
3.342
red band gap 2.1 eV
[6]
Y2 PBr2
rhombohedral
a=3.9807 c=29.250
[7]
Ag6 PS5 Br
cubic
P 4 3m
a=10.3765 Z=4
1117.26
5.460
red
[4]
Cd5 P2 Br4
orthorhombic
Pna 21
a=12.189, b=7.7080, c=13.664
[8]
Sn24 P19.3 Br8
[9]
Sn17 Zn7 P22 Br8
cubic
Pm 3 n
a=10.7449
[10]
Sn24−x Inx P19.2+0.2x x <16
cubic
Pm 3 n
[11]
Si30+x P16–x Te8–x Brx x = 1–6.4
cubic
Pm 3 n
a=9.9720 - 10.0405
[12]
Ba2 PBr
hexagonal
R 3 m
a=4.67 c=23.3 Z=3
[1]
Ba2 P7 Br
monoclinic
P21 /m
a=6.294 b=6.835 c=11.850 β= 95.819 Z=2
507.2
3.742
orange
[13]
La2 PBr2
trigonal
P 3 m 1
a=4.311 c=11.000 Z=1
177.04
5.28
[7]
La3 Zn4 P6.6 Br0.8
orthorhombic
Cmcm
a=4.099 b=14.229 c=20.388 Z=4
1189.0
5.290
black
[14]
Eu2 PBr
R 3m
a = 4.385, c = 21.90, Z = 3
[15]
W4 (PBr)Br10
monoclinic
C 12/m 1
a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4
1715.16
dark green
[16]
Hg2 P3 Br
orthorhombic
Pbcn
a = 8.014, b = 8.902, c = 7.823, Z = 4
[17]
Hg7 P4 Br6
monoclinic
P 21 /c
a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2
879.3
7.582
brown
[18]
(Hg2 P)2 HgBr4
monoclinic
P 21
a=7.776 b=12.226 c=7.930 β=121.34 Z=2
643.9
7.141
discovered in 1907; bright yellow; air with light sensitive
[19]
[Hg7 P4 Br3 ](SnBr3 )
cubic
P 21 3
a=12.490 Z=4
[20]
References
^
a
b
c
d
e Hadenfeldt, Claus; Kosiol, Wilfried (1975-06-01).
"Darstellung und Eigenschaften von Phosphidbromiden des Calciums, Strontiums und Bariums / Preparation and Properties of Phosphide Bromides of Calcium, Strontium, and Barium" . Zeitschrift für Naturforschung B . 30 (5–6): 378–384.
doi :
10.1515/znb-1975-5-616 .
ISSN
1865-7117 .
S2CID
94967271 .
^ Freudenthaler, E.; Pfitzner, A. (1997-02-01). Freudenthaler, E.; Pfitzner, A. (eds.).
"Crystal structure of Cu 12 P 20 Br 10 , a polyphosphide containing a new phosphorus polymer" . Zeitschrift für Kristallographie - Crystalline Materials . 212 (2): 103–109.
Bibcode :
1997ZK....212..103F .
doi :
10.1524/zkri.1997.212.2.103 .
ISSN
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^ Freudenthaler, E (November 1997).
"Copper(I) halide-phosphorus adducts: a new family of copper(I) ion conductors" . Solid State Ionics . 101–103: 1053–1059.
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^
a
b Gao, Lihua; Wu, Xiaowen; Yang, Daqing; Tian, Xinyu; Xu, Jingjing; Zhang, Bingbing; Wu, Kui (2021).
"M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances" . Dalton Transactions . 50 (48): 17901–17905.
doi :
10.1039/D1DT03251H .
ISSN
1477-9226 .
PMID
34851337 .
S2CID
244148134 .
^ Nilges, S.; Nilges, T.; Haeuseler, H.; Pfitzner, A. (November 2004).
"(CuBr)2P8Se3: preparation, structural, and vibrational spectroscopic characterization of an adduct of P8Se3 cages to Cu2Br2 rhombs" . Journal of Molecular Structure . 706 (1–3): 89–94.
Bibcode :
2004JMoSt.706...89N .
doi :
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^ Dolyniuk, Juli-Anna; Tran, Nhon; Lee, Kathleen; Kovnir, Kirill (July 2015).
"Sr 2 P 7 X ( X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3-" . Zeitschrift für anorganische und allgemeine Chemie . 641 (8–9): 1422–1427.
doi :
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^
a
b Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01).
"Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds" . Zeitschrift für Naturforschung B . 62 (11): 1377–1382.
doi :
10.1515/znb-2007-1105 .
ISSN
1865-7117 .
S2CID
95077294 .
^ M.M., Shatruk; L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (2000).
"Cd5 P2 Br4 - the first cadmium analogue of salts of Millon's base" [Cd5 P2 Br4 - the first cadmium analogue of salts of Millon's base]. Zhurnal Neorganicheskoj Khimii (in Russian). 45 (4).
ISSN
0044-457X .
^ Stefanoski, S.; Reshetova, L. N.; Shevelkov, A. V.; Nolas, G. S. (July 2009).
"Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8" . Journal of Electronic Materials . 38 (7): 985–989.
Bibcode :
2009JEMat..38..985S .
doi :
10.1007/s11664-008-0644-8 .
ISSN
0361-5235 .
S2CID
135898461 .
^ Kovnir, Kirill A.; Shatruk, Mikhail M.; Reshetova, Lyudmila N.; Presniakov, Igor A.; Dikarev, Evgeny V.; Baitinger, Michael; Haarmann, Frank; Schnelle, Walter; Baenitz, Michael; Grin, Yuri; Shevelkov, Andrei V. (August 2005).
"Novel compounds Sn20Zn4P22−vI8 (), Sn17Zn7P22I8, and Sn17Zn7P22Br8: Synthesis, properties, and special features of their clathrate-like crystal structures" . Solid State Sciences . 7 (8): 957–968.
doi :
10.1016/j.solidstatesciences.2005.04.002 .
^ Reshetova, L. N.; Shevelkov, A. V. (January 2012).
"Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system" . Russian Chemical Bulletin . 61 (1): 28–32.
doi :
10.1007/s11172-012-0004-y .
ISSN
1066-5285 .
S2CID
95316491 .
^ Abramchuk, Nikolay S.; Carrillo-Cabrera, Wilder; Veremchuk, Igor; Oeschler, Niels; Olenev, Andrei V.; Prots, Yurii; Burkhardt, Ulrich; Dikarev, Evgeny V.; Grin, Juri; Shevelkov, Andrei V. (2012-11-05).
"Homo- and Heterovalent Substitutions in the New Clathrates I Si 30 P 16 Te 8– x Se x and Si 30+ x P 16– x Te 8– x Br x : Synthesis, Crystal Structure, and Thermoelectric Properties" . Inorganic Chemistry . 51 (21): 11396–11405.
doi :
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ISSN
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PMID
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^ Dolyniuk, Juli-Anna; Kovnir, Kirill (2013-08-26).
"Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures" . Crystals . 3 (3): 431–442.
doi :
10.3390/cryst3030431 .
ISSN
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^ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12).
"Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)" . Chemistry of Materials . 28 (13): 4741–4750.
doi :
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ISSN
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^ Hadenfeldt, C.; Held, W. (September 1986).
"Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI" . Journal of the Less Common Metals (in German). 123 (1–2): 25–35.
doi :
10.1016/0022-5088(86)90111-6 .
^ Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02).
"Cluster Harvesting in the WBr 6 –P System" . Inorganic Chemistry . 54 (3): 989–992.
doi :
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ISSN
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^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.).
"Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl" . Zeitschrift für Kristallographie - Crystalline Materials . 209 (7): 583–585.
Bibcode :
1994ZK....209..583S .
doi :
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ISSN
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^ Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (June 1993).
"Syntheses and Crystal Structure of Hg7P4Br6" . Journal of Solid State Chemistry . 104 (2): 177–180.
Bibcode :
1993JSSCh.104..177S .
doi :
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^ Shevelkov, Andrei V.; Mustyakimov, Marat Yu.; Dikarev, Evgeny V.; Popovkin, Boris A. (1996).
"(Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts" . Journal of the Chemical Society, Dalton Transactions (1): 147–148.
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^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry . 2002 (3): 547–553.
doi :
10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N .
Salts and covalent derivatives of the
bromide ion