| |
| Identifiers | |
|---|---|
| Properties | |
| Bi2Br9Cs3 | |
| Molar mass | 1535.813 g·mol−1 |
| Appearance | Yellow crystals |
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
| |
Caesium enneabromodibismuthate is an inorganic compound with the formula Cs3Bi2Br9. It is one of the coordination complexes formed by caesium, bismuth and bromine. [1] At room temperature, it is trigonal (P3m1) and it undergoes phase transformation to monoclinic phase (C12/c1) when the temperature is below 96 K. [2]
Preparation
Traditionally, it can be synthesized from a hydrobromic acid solution of stoichiometric amounts of caesium bromide and bismuth hydroxide or bismuth(III) oxide, [3] crystals are formed by cooling the hot, saturated solution. [4] It can also be obtained by reacting caesium bromide and bismuth(III) bromide in DMF, followed by vaporizing the solvent. [5] Its nanocrystals can be synthesized in 1-octadecene at 170 °C using caesium oleate and bismuth(III) bromide as precursors. [6]
References
- ^ Tran, Minh N.; Cleveland, Iver J.; Aydil, Eray S. (January 2021). "Physical vapor deposition of the halide perovskite CsBi2Br7". Journal of Vacuum Science & Technology A. 39 (1): 013409. doi: 10.1116/6.0000604. eISSN 1520-8559. ISSN 0734-2101. S2CID 234115452.
- ^ Tran, Minh N.; Cleveland, Iver J.; Aydil, Eray S. (2020). "Resolving the discrepancies in the reported optical absorption of low-dimensional non-toxic perovskites, Cs3Bi2Br9 and Cs3BiBr6". Journal of Materials Chemistry C. 8 (30): 10456–10463. doi: 10.1039/d0tc02783a. eISSN 2050-7534. ISSN 2050-7526. S2CID 225578432.
- ^ Terao, Hiromitsu; Ishihara, Hideta; Okuda, Tsutomu; Yamada, Koji; Weiss, Alarich (1 December 1992). "Phase Transition in Cesium Enneabromodibismuthate(III), Cs3Bi2Br9; an 81Br and 209Bi NQR Study". Zeitschrift für Naturforschung A. 47 (12): 1259–1261. doi: 10.1515/zna-1992-1217. eISSN 1865-7109. ISSN 0932-0784. S2CID 197265206.
- ^ Timmermans, C. W. M.; Blasse, G. (1 August 1981). "On the Luminescence of Cs3Bi2Br9 Single Crystals". Physica Status Solidi B (in German). 106 (2): 647–655. doi: 10.1002/pssb.2221060230. eISSN 1521-3951. ISSN 0370-1972.
- ^ Romani, Lidia; Speltini, Andrea; Dibenedetto, Carlo Nazareno; Listorti, Andrea; Ambrosio, Francesco; Mosconi, Edoardo; Simbula, Angelica; Saba, Michele; Profumo, Antonella; Quadrelli, Paolo; De Angelis, Filippo; Malavasi, Lorenzo (6 September 2021). "Experimental Strategy and Mechanistic View to Boost the Photocatalytic Activity of Cs3Bi2Br9 Lead-Free Perovskite Derivative by g-C3N4 Composite Engineering". Advanced Functional Materials. 31 (46): 2104428. doi: 10.1002/adfm.202104428. eISSN 1616-3028. hdl: 11584/334481. ISSN 1616-301X.
- ^ Ghosh, Sirshendu; Mukhopadhyay, SankhaSubhra; Paul, Sumana; Pradhan, Bapi; De, Subodh Kumar (15 October 2020). "Control Synthesis and Alloying of Ambient Stable Pb-Free Cs3Bi2Br9(1–x)I9x (0 ≤ x ≤ 1) Perovskite Nanocrystals for Photodetector Application". ACS Applied Nano Materials. 3 (11): 11107–11117. doi: 10.1021/acsanm.0c02288. eISSN 2574-0970. ISSN 2574-0970. S2CID 228958674.