Chemistry of organometallic compounds containing an neptunium-carbon bond
Organoneptunium chemistry is the
chemical science exploring the properties, structure, and reactivity of organoneptunium compounds, which are
organometallic compounds containing a
carbon to
neptuniumchemical bond.[1] Several such compounds exist even though the element itself, neptunium, is man-made and highly
radioactive: tricyclopentadienylneptunium-chloride,[2][3] tetrakis(cyclopentadienyl)neptunium(IV)[4] and
neptunocene Np(C8H8)2.
^Organometallic Neptunium Chemistry Polly L. Arnold, Michał S. Dutkiewicz, and Olaf Walter Chemical Reviews Article ASAP
doi:
10.1021/acs.chemrev.7b00192
^Über die Existenz von Tri-cyclopentadienyl-neptunium(IV)-halogenid F. BaumgärtnerE. O. FischerP. Laubereau Naturwissenschaften January 1965, Volume 52, Issue 20, pp 560–560
doi:
10.1007/BF00631569
^Tricyclopentadienylneptunium-chlorid E.O.Fischer P.Laubereau F.Baumgärtner B.Kanellakopulos Journal of Organometallic Chemistry Volume 5, Issue 6, June 1966, Pages 583-584
doi:
10.1016/S0022-328X(00)85165-7
^Baumgärtner, F., Fischer, E. O., Kanellakopulos, B. and Laubereau, P. (1968), Tetrakis(cyclopentadienyl)neptunium(IV). Angew. Chem. Int. Ed. Engl., 7: 634.
doi:
10.1002/anie.196806341