Thiazyl trifluoride is a
chemical compound of
nitrogen,
sulfur, and
fluorine, having the
formulaNSF3. It exists as a stable, colourless gas, and is an important precursor to other sulfur-nitrogen-fluorine compounds.[2] It has
tetrahedral molecular geometry around the sulfur atom, and is regarded to be a prime example of a compound that has a sulfur-nitrogen
triple bond.[3]
^Oskar Glemser and Rüdiger Mews (1980). "Chemistry of Thiazyl Fluoride (NSF) and Thiazyl Trifluoride (NSF3): A Quarter Century of Sulfur-Nitrogen-Fluorine Chemistry". Angew. Chem. Int. Ed. Engl.19 (11): 883–899.
doi:
10.1002/anie.198008831.
^Borrmann, T.; Lork, E.; Mews, R. D.; Parsons, S.; Petersen, J.; Stohrer, W. D.; Watson, P. G. (2008). "The crystal structures of NSF 3 and (NSF2N(CH3)CH2–)2: How short is the 'Crystallographic' N≡S triple bond?". Inorganica Chimica Acta. 361 (2): 479–486.
doi:
10.1016/j.ica.2007.05.016.
^Steve Mitchell (1996). Steve Mitchell (ed.). Biological interactions of sulfur compounds. CRC Press. p. 14.
ISBN0-7484-0245-4.
^Huheey, James E.; Keiter, Ellen A.; Keiter, Richard L. (2003). Anorganische Chemie (in German). Berlin: Walter de Gruyter. p. 1021.
ISBN978-3-11-017903-3.
^US patent 3,666,784, Alan F. Clifford, Thomas C. Rhyne and James W. Thompson, "Process For Preparing .alpha.,.alpha.-Fluorinated Alkyl Isocyanates", issued 1972-05-30