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Rhodium(III) hydroxide
Identifiers
ChemSpider
ECHA InfoCard
100.040.447
EC Number
InChI=1S/3H2O.Rh/h3*1H2;/q;;;+3/p-3
Key: KTEDZFORYFITAF-UHFFFAOYSA-K
Properties
H 3 O 3 Rh
Molar mass
153.926 g·mol−1
Hazards
GHS labelling :
Warning
H302 ,
H312 ,
H315 ,
H319 ,
H332 ,
H335 ,
H413
P261 ,
P264 ,
P270 ,
P271 ,
P273 ,
P280 ,
P301+P312 ,
P302+P352 ,
P304+P312 ,
P304+P340 ,
P305+P351+P338 ,
P312 ,
P321 ,
P322 ,
P330 ,
P332+P313 ,
P337+P313 ,
P362 ,
P363 ,
P403+P233 ,
P405 ,
P501
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Rhodium(III) hydroxide is a chemical compound with the formula Rh(OH)3 .
Various compounds of rhodium(III) with hydroxide ligands are known.
[1]
Some
double
hydroxides called rhodium(III)
hydrogarnets are known to exist. They include BaNaRh(OH)6 , Ca3 Rh2 (OH)12 , Sr3 Rh2 (OH)12 .
[2] and Ba3 [Rh(OH)6 2 ⋅ H2 O.
[3]
Ga[Rh(OH)6 (Mo6 O18 )](H2 O)16 is a complex
molybdate hydroxide.
[4]
References
^ Spiccia, Leone (July 2004).
"Homopolynuclear and heteropolynuclear Rh(III) aqua ions – a review" . Inorganica Chimica Acta . 357 (10): 2799–2817.
doi :
10.1016/j.ica.2003.12.036 .
^ Cook, Daniel S.; Clarkson, Guy J.; Dawson, Daniel M.; Ashbrook, Sharon E.; Fisher, Janet M.; Thompsett, David; Pickup, David M.; Chadwick, Alan V.; Walton, Richard I. (2018-09-04).
"Alkaline-Earth Rhodium Hydroxides: Synthesis, Structures, and Thermal Decomposition to Complex Oxides" . Inorganic Chemistry . 57 (17): 11217–11224.
doi :
10.1021/acs.inorgchem.8b01797 .
hdl :
10023/18311 .
ISSN
0020-1669 .
PMID
30106569 .
S2CID
52004001 .
^ Albrecht, Ralf; Bretschneider, Vincent; Doert, Thomas; Ruck, Michael (2021-04-08).
"Ba 3 [Rh(OH) 6 ] 2 ⋅ H 2 O – a Precursor to Barium Oxorhodates with One‐dimensional Hydrogen Bonding Systems" . Zeitschrift für anorganische und allgemeine Chemie . 647 (18): 1702–1708.
doi :
10.1002/zaac.202100016 .
^ Kaziev, G. Z.; Osminkina, I. V.; Kin'ones, Saul' O.; Bel'skij, V. K.; Zavodnik, V. E. (2002).
"Synthesis, thermal analysis, IR spectra, and crystal structure of gallium hexamolybdorhodate(3)" . Zhurnal Neorganicheskoj Khimii (in Russian). 47 (1): 18–22.
ISSN
0044-457X .
Rh(0)
Rh(I)
Rh(II) Organorhodium(II) compunds
Rh(III) Organorhodium(III) compunds
Rh(IV) Rh(V) Rh(VI)