Joseph Louis Proust (26 September 1754 – 5 July 1826) was a
Frenchchemist. He was best known for his discovery of the
law of definite proportions in 1794, stating that chemical compounds always combine in constant proportions.[1]
Life
Joseph L. Proust was born on 26 September 1754 in
Angers,
France. His father served as an apothecary in Angers. Joseph studied chemistry in his father's shop and later went to Paris where he gained the appointment of apothecary in chief to the
Salpêtrière.[2] He also taught chemistry with
Pilâtre de Rozier, a famous aeronaut.[2]
Under
Carlos IV's influence Proust went to
Spain. There he taught at the Chemistry School in
Segovia and at the
University of Salamanca.
But when Napoleon invaded Spain, they burned Proust's laboratory and forced him back to France. On 5 July 1826 he died in Angers,
France. The mineral
proustite (Ag3AsS3) is named in his honour.
Proust's largest accomplishment in the realm of science was disproving Berthollet[2] with the
law of definite proportions, which is sometimes also known as Proust's Law.[1] Proust studied
copper carbonate, the two tin oxides, and the two iron sulfides to prove this law. He did this by making artificial copper carbonate and comparing it to natural copper carbonate. With this he showed that each had the same proportion of weights between the three elements involved (
Cu,
C,
O).[3] Between the two types of the other
compounds, Proust showed that no intermediate compounds exist between them. Proust published this paper in 1794, but the law was not accepted until 1812, when the Swedish chemist
Jöns Jacob Berzelius gave him credit for it.[citation needed]
There are, however, exceptions to the Law of Definite Proportions. An entire class of substances does not follow this rule. The compounds are called
non-stoichiometric compounds, or Berthollides, after Berthollet. The ratio of the elements present in the compound can fluctuate within certain limits, such as for example
ferrous oxide. The ideal formula is FeO, but due to
crystallographic vacancies it is reduced to about Fe0.95O.[citation needed]
Proust was also interested in studying the sugars that are present in sweet vegetables and fruits. In 1799, Proust demonstrated, to his class in
Madrid, how the sugar in
grapes is identical to that found in
honey.
Works
Joseph Louis Proust (1794).
"Recherches sur le Bleu de Prusse" [Research on Prussian Blue]. Journal de Physique, de Chimie, et d'Histoire Naturelle (in French). 2: 334–341.
Joseph Louis Proust (1798).
"Analyse d'une Mine d'Argent d'Amérique" [Analysis of a silver mine in America]. Journal de Physique, de Chimie, et d'Histoire Naturelle (in French). 3: 389–391.
Joseph Louis Proust (1799).
"Sur la manganèse des cendres végétales" [On the manganese of vegetable ash]. Journal de Physique, de Chimie, et d'Histoire Naturelle (in French). 48: 469.
Joseph Louis Proust (1800).
"Recherches sur l'étain" [Research on tin]. Journal de Physique, de Chimie, et d'Histoire Naturelle (in French). 51: 173–184.
Joseph Louis Proust (1801).
"Faits détachés sur la platine" [Isolated facts on platinum]. Journal de Physique, de Chimie, et d'Histoire Naturelle (in French). 52: 409–438.
Joseph Louis Proust (1802).
"Sur les sulfures natifs et artificiels du fer" [On the natural and artificial iron sulfides]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 54: 89–96.
Joseph Louis Proust (1803).
"Sur le nickel" [On nickel]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 57: 169–174.
Joseph Louis Proust (1804).
"Sur le bouillon d'os" [On bone broth]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 59: 114–122.
Joseph Louis Proust (1804).
"Sur les sulfures métalliques" [On the metallic sulfurs]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 59: 260–265.
Joseph Louis Proust (1804).
"Sur les sulfures alkalins" [On the alkaline sulfurs]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 59: 265–273.
Joseph Louis Proust (1804).
"Sur les oxidations métalliques" [On metal oxides]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 59: 321–342.
Joseph Louis Proust (1804).
"Sur le sulfate de cuivre, au minimum d'acide" [On copper sulfate, at the minimum of acid]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 59: 343–350.
Joseph Louis Proust (1804).
"Sur les muriates de cuivre verd et blanc" [On the green and white muriates of copper]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 59: 350–355.
Joseph Louis Proust (1805).
"Étain et muriate d'ammoniaque" [Tin and muriate of ammonia]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 61: 338–349.
Joseph Louis Proust (1806).
"Sur l'utilité du Lichen d'Islande, comme aliment" [On the utility of Iceland lichen as a food]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 63: 81–97.
Joseph Louis Proust (1807).
"Sur la blende" [On blende]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 64: 150–154.
Joseph Louis Proust (1807).
"Des oxides de cuivre" [Some copper oxides]. Journal de Physique, de Chimie, d'Histoire Naturelle, et des Arts (in French). 65: 80–82.