James E. Webb (1906–1992), American official, the second Administrator of the National Aeronautics and Space Administration (NASA), namesake of the James Webb Space Telescope
James Webb (Royal Navy officer) (died 1761), commodore governor for the Canadian province of Newfoundland and Labrador for 1760
J. B. Webb (James B. Webb, 1929–2009), influential in shaping Australia's international relations and aid during the 1950s, 60s and 70s
Jim Webb (born 1946), former senator from Virginia, former U.S. Secretary of the Navy, and 2016 presidential candidate
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